magnesium in tetrahydrofuran; toluene soln. of β-fenchyl chloride in THF wasadded to suspn. of Mg in THF,refluxed for 12 h, separated from Mg via cannula, Ph3SnCl was added; detected by 119Sn NMR;
参考文献
Organic and Biomolecular Chemistry, , vol. 7, # 1 p. 41 - 42
magnesium in tetrahydrofuran; toluene soln. of α-fenchyl chloride in THF wasadded to suspn. of Mg in THF, refluxed for 12 h, separated from Mg via cannula, Ph3SnCl was added; detected by 119Sn NMR;
参考文献
Organic and Biomolecular Chemistry, , vol. 7, # 1 p. 41 - 42
magnesium in tetrahydrofuran; toluene soln. of bornyl chloride in THF was added to suspn. of Mg in THF, refluxed for 12 h, separated from Mg via cannula, distilled while toluene was constantly added to replace THF, kept at 111°C for 12 h, Ph3SnCl was added; detected by 119Sn NMR;
参考文献
Organic and Biomolecular Chemistry, , vol. 7, # 1 p. 41 - 42
magnesium in tetrahydrofuran soln. of isobornyl chloride in THF was added to suspn. of Mg in THF, refluxed for 12 h, separated from Mg via cannula, Ph3SnCl was added; detected by 119Sn NMR;
参考文献
Organic and Biomolecular Chemistry, , vol. 7, # 1 p. 41 - 42
sodium perchlorate in ethanol; water (N2); titration of soln. of Ph3SnCl with 0.1 M NaOH in aq. ethanol at 25°C and ionic strength of 0.1 M NaClO4; monitoring by spectrophotometric and potentiometric techniques;
参考文献
Canadian Journal of Chemistry, , vol. 86, # 8 p. 751 - 756
