1.1: 4-(N,N-dimethlyamino)pyridine / acetonitrile / 12 h / 20 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 12 h / 0 - 20 °C 3.1: trifluoroacetic acid / dichloromethane / 12 h / 0 - 20 °C 4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 °C 4.2: 12 h / 0 - 20 °C View Scheme

1: 4-(N,N-dimethlyamino)pyridine / acetonitrile / 12 h / 20 °C 2: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 12 h / 0 - 20 °C 3: trifluoroacetic acid / dichloromethane / 12 h / 0 - 20 °C View Scheme

T=750°C; P=0.001 Torr; 0.333333 h; pyrolysis of o-substituted N-, O-, and S-allyl compounds; Mechanism;

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1: 2-amino-benzenethiol With potassium tert-butylate in ethanol T=0°C; 0.0833333 h; 2: 2-iodo-propane in ethanol Further stages.;

sodium hydroxide in ethanol

trifluorormethanesulfonic acid; trifluoroacetic acid Ambient temperature;