(R)-(-)-10-甲基-1(9)-辛基-2-酮合成路线 （共 14 条）
反应条件
methanol; sodium methylate T=35°C; 1 h;
参考文献
Pfau, Michel; Revial, Gilbert; Guingant, Andre; d'Angelo, Jean
Journal of the American Chemical Society, 1985 , vol. 107, # 1 p. 273 - 274
反应条件
(S)-1-phenyl-ethylamine
参考文献
Doering, W. Von E.; Birladeanu, Ludmila; Sarma, Keshab; Shao, Li-Sming
Journal of the American Chemical Society, 1996 , vol. 118, # 28 p. 6660 - 6665
反应条件
1: tetrahydrofuran / 72 h / 20 °C 2: 88 percent / 10 percent AcOH / 1 h / 20 °C 3: 94 percent / 5 percent MeONa/MeOH / 1 h / 35 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 107, # 1 p. 273 - 274
反应条件
1: O3 / -70 deg C, 3 h, then room temperature, 15 h 2: p-nitrobenzoyl chloride / pyridine / 19 h / Ambient temperature 3: p-TsOH*H2O / benzene / 2 h / Heating 4: hydrogen / 2percent Pd/SrCO3 / ethanol View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 52, # 8 p. 2043 - 2048
反应条件
1: 62 percent / PTSA / Heating 2: O2, PdCl2, CuCl2 / H2O; dimethylformamide 3: 2percent NaOH / methanol; H2O View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 1 p. 43 - 44
反应条件
1: O2, PdCl2, CuCl2 / H2O; dimethylformamide 2: 2percent NaOH / methanol; H2O View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 1 p. 43 - 44
反应条件
1: 1.) O3, 2.) NaI / 1.) MeOH, CH2Cl2, -73 deg C, 5 h, 2.) MeOH, CH2Cl2, AcOH, 0 deg C, 15 min, and room temperature, 1 h 2: 5.08 g / m-chloroperbenzoic acid / CH2Cl2 / 96 h / Ambient temperature 3: Jones reagent / acetone / 0.83 h / Ambient temperature 4: 3.47 g / p-TsOH*H2O / benzene / 2 h / Heating 5: hydrogen / 2percent Pd/SrCO3 / ethanol View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 52, # 8 p. 2043 - 2048
反应条件
hydrogen; Pd/SrCO3 in ethanol Yield given;
参考文献
Agricultural and Biological Chemistry, , vol. 52, # 8 p. 2043 - 2048
反应条件
1: 5.08 g / m-chloroperbenzoic acid / CH2Cl2 / 96 h / Ambient temperature 2: Jones reagent / acetone / 0.83 h / Ambient temperature 3: 3.47 g / p-TsOH*H2O / benzene / 2 h / Heating 4: hydrogen / 2percent Pd/SrCO3 / ethanol View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 52, # 8 p. 2043 - 2048
反应条件
1: p-TsOH*H2O / benzene / 2 h / Heating 2: hydrogen / 2percent Pd/SrCO3 / ethanol View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 52, # 8 p. 2043 - 2048
