jones reagent in acetone T=0°C; 0.166667 h;

暂无反应条件数据

1: NaHCO3 / H2O; toluene / 16 h / 20 °C 2: 92 percent / Jones reagent / acetone / 0.17 h / 0 °C View Scheme

1: NaBH4 2: HBr, AcOH 4: 1) DAST, 2) RuO4 5: 1) HCl, 2) Ag2O View Scheme

1: 6.8 g / SOCl2 / 20 h / Heating 2: 3.86 g / p-toluenesulfonic acid / acetic acid / 44 h / Heating 3: 6.3 g / 20percent HBr/glacial acetic acid / 2 h / Ambient temperature 4: 3.64 g / 2.5 N aq. NaOH / methanol / 18 h / Ambient temperature 5: 1.) N,N-disuccinimidyl carbonate, pyridine, 2.) NEt3 / 1.) CH3CN, RT, 44 h, 2.) CH3CN, H2O, RT 6: 0.4 g / conc. aq. HCl / acetonitrile / 10 h / 5 °C View Scheme

1: NaH / dimethylsulfoxide / 1.) 70 deg C, 2.) 70 deg C, 4 h, 3.) overnight 2: 89 percent / H2 / 5percent Pd/C / methanol View Scheme

1: 6.8 g / SOCl2 / 20 h / Heating 2: 3.86 g / p-toluenesulfonic acid / acetic acid / 44 h / Heating 3: 6.3 g / 20percent HBr/glacial acetic acid / 2 h / Ambient temperature 4: 3.64 g / 2.5 N aq. NaOH / methanol / 18 h / Ambient temperature 5: 1.) N,N-disuccinimidyl carbonate, pyridine, 2.) NEt3 / 1.) CH3CN, RT, 44 h, 2.) CH3CN, H2O, RT View Scheme

1: NaBH(OAc)3 View Scheme

1: NaBH4 / methanol; H2O / 20 h / -5 °C 2: 83 percent / p-toluenesulfonic acid / 36 h / Heating 3: 80 percent / pyridine / CHCl3 / 168 h / Ambient temperature 4: 70 percent / dimethylsulfoxide / 3 h / 80 °C 5: 94 percent / HCl / 96 h 6: 100 percent / 4 M NaOH / tetrahydrofuran; H2O / 0.92 h 7: 75 percent / H2 / 10percent Pd/C / methanol / 0.5 h / 2482.3 - 2585.7 Torr View Scheme

1: NaBH4 2: HBr, AcOH View Scheme