1: aniline With hydrogenchloride; sodium nitrite in water T=0 - 5°C; 2: With sodium tetrafluoroborate in water 0.166667 h; 3: potassium p-toluenetrifluoroborate With palladium diacetate; sodium carbonate in water T=25°C; Suzuki-Miyaura Coupling; 6 h;
1: p-toluidine With hydrogenchloride; sodium nitrite in water T=25°C; 2: With sodium tetrafluoroborate in water 0.166667 h; 3: PhBF3(-)K(+) With palladium diacetate; sodium carbonate in water T=25°C; Suzuki-Miyaura Coupling; 6 h;
1: With iron; zinc(II) iodide; zinc; CoBr2{N-[(pyridin-2-yl)methylene]methanesulfonamide} in dichloromethane T=20°C; Diels-Alder reaction; 24 h; 2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in benzene T=20°C;
参考文献
Angewandte Chemie - International Edition, , vol. 45, # 31 p. 5204 - 5206
