3,4,5-三甲氧基甲苯合成路线 （共 96 条）
反应条件
N,N,N',N'-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a;2',1'-c][1,4] diazepine-2,12-diamine in N,N-dimethyl-formamide 72 h; Inert atmosphereGloveboxUV-irradiation;
参考文献
Doni, Eswararao; O'Sullivan, Steven; Murphy, John A.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2239 - 2242
Angew. Chem., 2013 , vol. 125, # 8 p. 2295 - 2298,4
反应条件
1: With naphthalene; lithium in tetrahydrofuran T=-50°C; 16 h; 2: With water in tetrahydrofuran Further stages.;
参考文献
Tetrahedron, , vol. 63, # 48 p. 11998 - 12006
反应条件
copper(l) chloride in methanol; N,N-dimethyl-formamide T=140°C; 8 h; Autoclave; TemperatureTime;
参考文献
Organic Process Research and Development, , vol. 10, # 3 p. 487 - 492
反应条件
1: bromine / 1,2-dichloro-ethane / 7 h / 20 - 25 °C 2: sodium hydroxide / water; 1,2-dichloro-ethane / 5 h / 30 - 35 °C 3: copper(l) chloride / methanol; N,N-dimethyl-formamide / 7 h / 70 - 105 °C View Scheme
参考文献
Organic Process Research and Development, , vol. 10, # 3 p. 487 - 492
反应条件
1: 85 percent / K3Fe(CN)6; 25 percent NH4OH / H2O; CH2Cl2 / 4 h / 20 °C 2: 65 percent / Zn-Hg / acetic acid; toluene; H2O / 0.75 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 31, # 5 p. 657 - 660
反应条件
1: n-butyllithium / tetrahydrofuran / -78 °C / |Inert atmosphere 2: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethylene glycol dimethyl ether; water / |Inert atmosphere; |Reflux View Scheme
参考文献
Helvetica Chimica Acta, , vol. 95, # 12 p. 2680 - 2694
反应条件
sodium hydroxide T=70 - 80°C;
参考文献
Helvetica Chimica Acta, , vol. 9, p. 656,662
Helvetica Chimica Acta, , vol. 16, p. 283
反应条件
1-methyl-4-isopropyl-1-cyclohexene; palladium on activated charcoal
参考文献
Chemische Berichte, , vol. 99, p. 227 - 232
反应条件
lithium aluminium tetrahydride in tetrahydrofuran Heating;
参考文献
Chemische Berichte, , vol. 95, p. 2837 - 2843
反应条件
1: Zn, 4 N HCl / ethanol / 1 h / Heating 2: conc. H2SO4, amylnitrite / ethanol / 0.67 h / 0 °C 3: H2(18)O / cyclohexane / 1.5 h / Heating 4: K2CO3 / acetone / 2 h / Heating View Scheme
参考文献
Chemische Berichte, , vol. 114, # 5 p. 1963 - 1966
