tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethylene glycol dimethyl ether T=80°C; 16 h;

1: 4-bromo-phenol With di-isopropyl azodicarboxylate; triphenylphosphine; Wang resin in tetrahydrofuran T=20°C; 2: dihydroxy(3-fluorophenyl)borane With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether; water T=80°C; Suzuki reaction; 3: With trifluoroacetic acid in dichloromethane 0.166667 h;

Cunninghamella elegans in dimethyl sulfoxide 72 h; Microbiological reaction;

1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / water; toluene / |Reflux 2: Cunninghamella elegans / dimethyl sulfoxide / 72 h / |Microbiological reaction View Scheme

T=30°C; 20 h; Irradiation; Product distribution;

T=45°C; 20 h; Irradiationother reagents and temperature; Product distribution;