in further solvent(s)
addn. of (CH3)3Pb(OCOCF3) (50 mmol) in portions to (CF3)2Cd*D (25 mmol) in 1,6-dibromohexane at 70°C with stirring;; product mixt. in equimlar ratio obtained (identified by 1H-, 19F-, 13C- and 207Pb-NMR);;
参考文献
Eujen, R.; Patorra, A.
Journal of Organometallic Chemistry, 1992 , vol. 438, # 1.2 p. 57 - 75
Br2 in neat (no solvent)
byproducts: MeBr, CF3Br; absence of air and moisture; condensation of 1 equiv. Br2 to Pb-compd., slow warming to room temp.; not isolated, detd. by (1)H- and (19)F-NMR spectroscopy;
参考文献
Eujen, Reint; Lagow, Richard J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1978 , p. 541 - 544
