3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇合成路线 （共 69 条）
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇
反应条件
1: With sulfuric acid; sulfur trioxide T=20 - 80°C; 1.66 h; 2: With sodium sulfite; water T=20 - 80°C; 2 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: US2009/118552 A1, 2009 ;
Location in patent: Page/Page column 6 ;
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇
反应条件
1: With sulfuric acid; sulfur trioxide T=20 - 80°C; 1.33 h; 2: With water T=20 - 80°C; 1.5 - 2 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: US2009/118552 A1, 2009 ;
Location in patent: Page/Page column 6 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
1: With monochloroborane in diethyl ether 24 h; 2: With dihydrogen peroxide in diethyl ether alkaline solution; Further stages.;
参考文献
Chemical Communications, , # 4 p. 386 - 387
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇
反应条件
trifluorormethanesulfonic acid; water T=20°C; 0.166667 h;
参考文献
Paterova, Jana; Skalicky, Martin; Rybackova, Marketa; Kvicalova, Magdalena; Cvacka, Josef; Kvicala, Jaroslav
Journal of Fluorine Chemistry, 2010 , vol. 131, # 12 p. 1338 - 1343
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
pyrrolidin-2-one in toluene T=140°C; 24 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 8-9 ;
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
in N,N-dimethyl-formamide T=150°C; 24 h;
参考文献
Journal of Fluorine Chemistry, , vol. 31, p. 151 - 174
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
sodium hydroxide in ethanol T=30°C; variation of condition; also with NaOMe; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 49, # 13 p. 2361 - 2368
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇
反应条件
1.1: LDA / tetrahydrofuran / 0.75 h / -78 °C 1.2: tetrahydrofuran / 3 h / -78 °C 1.3: 78 percent / tetrahydrofuran / -78 °C 2.1: LiHBEt3 / tetrahydrofuran / 2 h / 20 °C View Scheme
参考文献
Molecules, , vol. 9, # 5 p. 266 - 277
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; formamide T=150°C; 6 h;
参考文献
Journal of Organic Chemistry, , vol. 58, # 7 p. 1804 - 1811
