1-(1-氟乙基)-4-硝基苯合成路线 （共 6 条）
反应条件
tetra(n-butyl)ammonium hydrogensulfate; triphenyl tin fluoride in acetonitrile
T=85°C; 10 h;
参考文献
Makosza, Mieczyslaw; Bujok, Robert
Tetrahedron Letters, 2002 , vol. 43, # 15 p. 2761 - 2763
反应条件
potassium fluoride; tetra(n-butyl)ammonium hydrogensulfate; triphenyl tin fluoride in acetonitrile
参考文献
Makosza; Bujok
Journal of Fluorine Chemistry, 2005 , vol. 126, # 2 p. 209 - 216
反应条件
diethylamino-sulfur trifluoride; [C8mim][PF6]
T=20°C; 0.5 h;
参考文献
Das, Saibal; Chandrasekhar, Srivari; Yadav, Jhillu Singh; Gree, Rene
Tetrahedron Letters, 2007 , vol. 48, # 30 p. 5305 - 5307
反应条件
potassium carbonate; triethylamine tris(hydrogen fluoride) in toluene
T=110°C; 3 h; Inert atmosphere;
参考文献
Yadav, Arvind K.; Srivastava, Vishnu P.; Yadav, Lal Dhar S.
Chemical Communications, 2013 , vol. 49, # 21 p. 2154 - 2156
反应条件
pyridine; hydrogen fluoride
T=25°C; 4.07 h; electrochemical synthesis: Pt electrodes, applied potential 2.25 V, frequency square wave alternating current of 0.033 Hz, passed charge of 2.25 F mol-1;
参考文献
Lee, Sarah M.; Roseman, Jamie M.; Zartman, C. Blair; Morrison, Eamonn P.; Harrison, Sean J.; Stankiewicz, Corrie A.; Middleton
Journal of Fluorine Chemistry, 1996 , vol. 77, # 1 p. 65 - 70
反应条件
1: toluene / 1.5 h / 80 °C
2: potassium carbonate; triethylamine tris(hydrogen fluoride) / toluene / 3 h / 110 °C / |Inert atmosphere
View Scheme
参考文献
Yadav, Arvind K.; Srivastava, Vishnu P.; Yadav, Lal Dhar S.
Chemical Communications, 2013 , vol. 49, # 21 p. 2154 - 2156
