2,2'thiodiethanol in ethanol dissolving 0.0027mmol of tetrachloroauric acid in 40ml EtOH, reducing with 2,2'thiodiethanol (0.038mol), 2h stirring (until becomming almost colorless); addg. of a stoichiometric amt. of Cy2PhP inside a glove bag (N2);; vacuum filtn.; elem. anal.;;
Abdur-Rashid, Kamaluddin; Fong, Tina P.; Greaves, Bronwyn; Gusev, Dmitry G.; Hinman, Justin G.; Landau, Shaun E.; Lough, Alan J.; Morris, Robert H.
Journal of the American Chemical Society, 2000 , vol. 122, # 38 p. 9155 - 9171
→
反应条件
in dichloromethane-d2
T=20°C; Equilibrium constant;
参考文献
Li, Tianshu; Lough, Alan J.; Morris, Robert H.
Chemistry - A European Journal, 2007 , vol. 13, # 13 p. 3796 - 3803
