甲基2,6-环庚二烯-1-羧酸酯合成路线 (共 3 条)
反应条件
1: in tetrahydrofuran; dichloromethane
T=-70°C; 1 h;
2: With ammonium cerium(IV) nitrate in methanol
T=23°C; 0.166667 h;
3: in ethyl acetate
T=55 - 60°C; Cope rearrangement; 0.75 h;
参考文献
Waltock, Nathaniel J.; Donaldson, William A.
Organic Letters, 2005 , vol. 7, # 10 p. 2047 - 2049
反应条件
1: in tetrahydrofuran; dichloromethane
T=-70°C; 1 h;
2: With ammonium cerium(IV) nitrate in methanol
T=23°C; 0.166667 h; Title compound not separated from byproducts;
参考文献
Waltock, Nathaniel J.; Donaldson, William A.
Organic Letters, 2005 , vol. 7, # 10 p. 2047 - 2049
参考文献
Pikulik,I.; Childs,R.F.
Canadian Journal of Chemistry, 1977 , vol. 55, p. 251 - 258