3-氯-5-羟基-7-甲氧基萘醌合成路线 （共 13 条）
反应条件
(i) ClSiMe3, Et3N, benzene, (ii) /BRN= 635994/, K2CO3, acetone; Multistep reaction;
参考文献
Grandmaison,J.-L.; Brassard,P.
Journal of Organic Chemistry, 1978 , vol. 43, p. 1435 - 1438
反应条件
in tetrahydrofuran Ambient temperature;
参考文献
Savard, Jacques; Brassard, Paul
Tetrahedron, 1984 , vol. 40, # 18 p. 3455 - 3464
参考文献
Ross Kelly; Xu, Wei; Ma, Zhenkun; Li, Qun; Bhushan, Vidya; Merken
Journal of the American Chemical Society, 1993 , vol. 115, # 13 p. 5843 - 5844
反应条件
1: in tetrahydrofuran
T=-30 - 20°C; Diels-Alder cycloaddition reaction;
2: With silica gel in dichloromethane
24 h; Further stages.;
参考文献
Gattinoni, Sonia; Merlini, Lucio; Dallavalle, Sabrina
Tetrahedron Letters, 2007 , vol. 48, # 6 p. 1049 - 1051
反应条件
1: in tetrahydrofuran
T=-30 - 20°C; Diels-Alder reaction; 2.5 h;
2: With silica gel in dichloromethane
14 h; regioselective reaction;
参考文献
Dong, Wen-Kai; Huang, Xiong; Xu, Dong-Cheng; Lia, Xin-Sheng; Xie, Jian-Wu
Journal of the Brazilian Chemical Society, 2012 , vol. 23, # 2 p. 280 - 284
反应条件
hydrogenchloride; aluminium trichloride in nitrobenzene
参考文献
Grandmaison,J.-L.; Brassard,P.
Journal of Organic Chemistry, 1978 , vol. 43, p. 1435 - 1438
反应条件
in tetrahydrofuran
-30 deg C, 30 min, -30 deg C to RT, 1h;
参考文献
Savard, Jacques; Brassard, Paul
Tetrahedron, 1984 , vol. 40, # 18 p. 3455 - 3464
反应条件
(i), (ii) (pyrolysis), (iii) aq. HCl; Multistep reaction;
参考文献
Savard,J.; Brassard,P.
Tetrahedron Letters, 1979 , p. 4911 - 4914
参考文献
Gesson; Jacquesy; Renoux
Tetrahedron Letters, 1983 , vol. 24, # 27 p. 2761 - 2764
反应条件
1: tetrahydrofuran / 24 h / Heating
2: silica gel / benzene
View Scheme
参考文献
Boisvert, Louise; Brassard, Paul
Journal of Organic Chemistry, 1988 , vol. 53, # 17 p. 4052 - 4059
