(R)-(+)-三苯甲基缩水甘油醚合成路线 （共 12 条）
反应条件
triethylamine in dichloromethane T=0 - 20°C; 18.5 h;
参考文献
White, James D.; Lincoln, Christopher M.; Yang, Jongtae; Martin, William H. C.; Chan, David B.
Journal of Organic Chemistry, 2008 , vol. 73, # 11 p. 4139 - 4150
反应条件
potassium hydroxide in ethanol T=25°C; 8 h;
参考文献
Kim, Mahn-Joo; Choi, Yoon Kyung
Journal of Organic Chemistry, 1992 , vol. 57, # 5 p. 1605 - 1607
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in dichloromethane T=20°C; 5 h;
参考文献
Tetrahedron Letters, , vol. 47, # 37 p. 6689 - 6693
反应条件
(R,R)-Co(C6H10(NCHC(COOHex)COCH3)2); N,N-diethyltrimethylsilylamine in dichloromethane T=30°C; P=15001.5 Torr; 72 h; optical yield given as percent eeenantioselective reaction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 80, # 7 p. 1391 - 1401
反应条件
1: 47 percent / toluene / 108 h / Ambient temperature; lipase PS from Pseudomonas sp. 2: 86 percent / KOH / ethanol / 8 h / 25 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 57, # 5 p. 1605 - 1607
反应条件
1: 85 percent / triethylamine, 4-(dimethylamino)pyridine (DMAP) / CH2Cl2 / 24 h / 25 °C 2: 47 percent / toluene / 108 h / Ambient temperature; lipase PS from Pseudomonas sp. 3: 86 percent / KOH / ethanol / 8 h / 25 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 57, # 5 p. 1605 - 1607
反应条件
(R,R)-Co(C6H10(NCHC(COOHex)COCH3)2); N,N-diethyltrimethylsilylamine in dichloromethane T=30°C; P=15001.5 Torr; 72 h; optical yield given as percent eeenantioselective reaction;
参考文献
Yamada, Wataru; Kitaichi, Yasunori; Tanaka, Hirotaka; Kojima, Tomohide; Sato, Mitsuo; Ikeno, Taketo; Yamada, Tohru
Bulletin of the Chemical Society of Japan, 2007 , vol. 80, # 7 p. 1391 - 1401
反应条件
K(1-)*K(1+)*(15-crown-5)2 in tetrahydrofuran T=25°C; Product distribution; Further Variations:Reaction partnersratio of reaction partners and reagent;
参考文献
Grobelny, Zbigniew; Stolarzewicz, Andrzej; Morejko-Buz, Barbara; Maercker, Adalbert
Journal of Organometallic Chemistry, 2002 , vol. 660, # 1 p. 6 - 13
反应条件
water in dichloromethane; acetonitrile T=0 - 20°C; Resolution of racemate;
参考文献
Journal of the American Chemical Society, , vol. 134, # 19 p. 8058 - 8061
反应条件
(R,R)-Co(C6H10(NCHC(COOHex)COCH3)2); N,N-diethyltrimethylsilylamine in dichloromethane T=30°C; P=15001.5 Torr; 72 h; optical yield given as percent eeenantioselective reaction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 80, # 7 p. 1391 - 1401
