n-C4H9Li in petroleum ether
addn. of n-C4H9Li (0.9 M in hexane) to soln. of hydrido complex at -20°C under atmosphere of C2H4, stirring, warming slowly to room temp. (red -> orange-yellow, white ppt. formed), 30-40 min; centrifugation, washing solid with Et2O, drying in vac. (lithium propionate), ethene complex isolated from soln.;
参考文献
Alvarez, Rafael; Carmona, Ernesto; Galindo, Agustin; Gutierrez, Enrique; Marin, Jose M.; et al.
Organometallics, 1989 , vol. 8, p. 2430 - 2439
hydrogen; platinum in water
T=10 - 40°C; Ea; KineticsThermodynamic data;
参考文献
Volkova, L. D.; Vyaznikovtseva, O. V.; Gabdrakipov, V. Z.; Sokol'skii, D. V.
Russian Journal of Physical Chemistry, 1984 , vol. 58, # 11 p. 1650 - 1652
Zhurnal Fizicheskoi Khimii, 1984 , vol. 58, p. 2719 - 2721