2,6-二甲基-1,4-苯二酚合成路线 （共 58 条）
反应条件
sodium dithionite in diethyl ether; water
参考文献
Weerapreeyakul, Natthida; Visser, Petra; Brummelhuis, Mathijn; Gharat, Laxmikant; Chikhale, Prashant J.
Medicinal Chemistry Research, 2000 , vol. 10, # 3 p. 148 - 163
反应条件
dihydrogen peroxide; Ti-superoxide in water; acetic acid T=50 - 60°C; 1.25 h; Product distribution / selectivity;
参考文献
WO2005/63664 A1, ;
Page/Page column 7; Table 1 ;
反应条件
cis-bisglycinato copper(II) monohydrate; dihydrogen peroxide T=70°C; Oxidation; 4 h;
参考文献
Puzari; Baruah, Jubaraj B.
Journal of Organic Chemistry, 2000 , vol. 65, # 8 p. 2344 - 2349
反应条件
7,8-difluoro-1,3-dimethyl-5-ethyl-4a-hydroperoxyalloxazine; dihydrogen peroxide; sodium hydrogencarbonate in methanol; water T=20°C; Dakin oxidation; 0.333333 h;
参考文献
Chen, Shuai; Hossain, Mohammad S.; Foss, Frank W.
Organic Letters, 2012 , vol. 14, # 11 p. 2806 - 2809
反应条件
1: With polyethylene glycol; carbon; copper(II) nitrate; anhydrous magnesium carbonate T=390 - 480°C; P=760.051 Torr; 24.25 h; Calcination; 2: methanol; hydroquinone With water in ethylene glycol dimethyl ether T=465 - 480°C; 10 - 24 h; Gas phase; Product distribution / selectivity;
参考文献
WO2005/97721 A1, ;
Page/Page column 9-10 ;
反应条件
boron tribromide in dichloromethane T=20°C; 0.5 h;
参考文献
Organic Letters, , vol. 6, # 16 p. 2777 - 2779
反应条件
methyllithium in tetrahydrofuran; diethyl ether T=-78°C; 1 h;
参考文献
Tetrahedron Letters, , vol. 21, p. 701 - 704
反应条件
silica gel; pyridinium chlorochromate in dichloromethane T=20°C; 1 h;
参考文献
Organic and Biomolecular Chemistry, , vol. 3, # 19 p. 3479 - 3481
反应条件
hydrogenchloride; dihydrogen peroxide in acetonitrile T=50°C; 3 h; the excess of H2O2 was removed by catalytic hydrogenation using 10percent Pd-C;
参考文献
Rao, Darvasula V.; Stuber, Fred A.
Tetrahedron Letters, 1981 , vol. 22, # 25 p. 2337 - 2340
反应条件
diethyl-1,4-dihydro-2,6-dimethyl-3,5-pyridine dicarboxylate; 1,3-dimethyl-5-ethyl-4a-hydroperoxyalloxazine; oxygen; sodium hydrogencarbonate in water; acetonitrile T=20°C; Dakin Phenol Oxidation; 3 h;
参考文献
Organic Letters, , vol. 14, # 19 p. 5150 - 5153,4
