2,2-二氟-1,3-苯并二恶茂-5-甲醛合成路线 （共 14 条）
反应条件
methanol; sodium tetrahydroborate
参考文献
DAINIPPON SUMITOMO PHARMA CO., LTD.
Patent: US2012/225876 A1, 2012 ;
Location in patent: Page/Page column 59 ;
反应条件
palladium 10 on activated carbon; hydrogen in methanol
T=50°C; P=15001.5 Torr;
参考文献
Liu, Jing; Fitzgerald, Anne E.; Mani, Neelakandha S.
Synthesis (Germany), 2012 , vol. 44, # 15 p. 2469 - 2473
反应条件
10 platinum on carbon; hydrogen in methanol
T=50°C; P=760.051 Torr;
参考文献
Liu, Jing; Fitzgerald, Anne E.; Mani, Neelakandha S.
Synthesis (Germany), 2012 , vol. 44, # 15 p. 2469 - 2473
反应条件
1: sodium tetrahydroborate; methanol
2: thionyl chloride / dichloromethane / 3 h / 20 °C / Cooling with ice
View Scheme
参考文献
DAINIPPON SUMITOMO PHARMA CO., LTD.
Patent: US2012/225876 A1, 2012 ;
