in 1,2-dichloro-benzene T=180°C; 4 h; regioselective reaction;

in tetrahydrofuran (N2); addn. of a soln. of boron compd. in THF to a soln. of tin compd. in THF, stirring at room temp. for 1 h, refluxing for 3 h, addn. of water;

in 1,2-dichloro-benzene T=180°C; 2.5 h; Inert atmosphere;

in 1,2-dichloro-benzene T=180°C; 2.5 h; Inert atmosphere;

bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=80°C; Phenylation; 3 h;

palladium Stille reaction;

bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=100°C; 15 h;

in 1,2-dichloro-benzene T=180°C; 4 h; regioselective reaction;

bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=100°C; 15 h;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '3647881', constants.ctx, '0')">sodium</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '3587154', constants.ctx, '0')">ammonia</a> <br />&nbsp;Irradiation (UV/VIS); (CH3)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate esterwas added, the mixt. was UV-irradiated with stirring for 4 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;&nbsp;<br /> &nbsp;