in toluene
under N2; soln. of PhBCl2 (1.05 equiv) in toluene added dropwise to soln. of (CuMes)5*toluene in toluene at -78 °C; mixt. allowed to slowly warm to room temp. and subsequently kept at 60 °C for 2 h; after filtration all volatiles removed under high vac.; crude product purified by distn.;
参考文献
Sundararaman, Anand; Jaekle, Frieder
Journal of Organometallic Chemistry, 2003 , vol. 681, # 1-2 p. 134 - 142
ammonium hydroxide; sodium acetate in tetrahydrofuran; water
diazotized p-aminophenyldimesitylborane/THF added slowly to chilled THF/H2O soln. of benzenesulfonamide derivative and excess sodium acetate; ammonium hydroxide addn.; extn. with ethyl ether and water; evapn. of org. layer;
参考文献
Glogowski, M. E.; Williams, J.L.R.
Journal of Organometallic Chemistry, 1981 , vol. 216, # 1 p. 1 - 8
Mg in tetrahydrofuran
addn. of dimesitylfluoroborane to a Grignard soln., prepared from 1,3,5-tribromobenzene and Mg in THF, refluxing for to days; chromy. on SiO2;
参考文献
Okada, Keiji; Sugawa, Tadashi; Oda, Masaji
Journal of the Chemical Society, Chemical Communications, 1992 , # 1 p. 74 - 75
