1-甲烷磺酰基-11-羟基-3,6,9-三氧杂十一烷合成路线 （共 16 条）
反应条件
1: triphenylphosphine / tetrahydrofuran; water / 24 h / 20 °C / Inert atmosphere
2: silver(l) oxide / dichloromethane / Inert atmosphere
View Scheme
参考文献
Jalisatgi, Satish S.; Kulkarni, Vikas S.; Tang, Betty; Houston, Zachary H.; Lee, Mark W.; Hawthorne, M. Frederick
Journal of the American Chemical Society, 2011 , vol. 133, # 32 p. 12382 - 12385
反应条件
1: dichloromethane / Inert atmosphere
2: sodium azide / N,N-dimethyl-formamide / 110 °C / Inert atmosphere
3: hydrogenchloride; triphenylphosphine / diethyl ether / Inert atmosphere
4: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 6 h / 0 °C / Inert atmosphere
5: triphenylphosphine / tetrahydrofuran; water / 24 h / 20 °C / Inert atmosphere
6: silver(l) oxide / dichloromethane / Inert atmosphere
View Scheme
参考文献
Jalisatgi, Satish S.; Kulkarni, Vikas S.; Tang, Betty; Houston, Zachary H.; Lee, Mark W.; Hawthorne, M. Frederick
Journal of the American Chemical Society, 2011 , vol. 133, # 32 p. 12382 - 12385
反应条件
1: sodium azide / N,N-dimethyl-formamide / 110 °C / Inert atmosphere
2: hydrogenchloride; triphenylphosphine / diethyl ether / Inert atmosphere
3: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 6 h / 0 °C / Inert atmosphere
4: triphenylphosphine / tetrahydrofuran; water / 24 h / 20 °C / Inert atmosphere
5: silver(l) oxide / dichloromethane / Inert atmosphere
View Scheme
参考文献
Jalisatgi, Satish S.; Kulkarni, Vikas S.; Tang, Betty; Houston, Zachary H.; Lee, Mark W.; Hawthorne, M. Frederick
Journal of the American Chemical Society, 2011 , vol. 133, # 32 p. 12382 - 12385
反应条件
1: hydrogenchloride; triphenylphosphine / diethyl ether / Inert atmosphere
2: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 6 h / 0 °C / Inert atmosphere
3: triphenylphosphine / tetrahydrofuran; water / 24 h / 20 °C / Inert atmosphere
4: silver(l) oxide / dichloromethane / Inert atmosphere
View Scheme
参考文献
Jalisatgi, Satish S.; Kulkarni, Vikas S.; Tang, Betty; Houston, Zachary H.; Lee, Mark W.; Hawthorne, M. Frederick
Journal of the American Chemical Society, 2011 , vol. 133, # 32 p. 12382 - 12385
反应条件
1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 6 h / 0 °C / Inert atmosphere
2: triphenylphosphine / tetrahydrofuran; water / 24 h / 20 °C / Inert atmosphere
3: silver(l) oxide / dichloromethane / Inert atmosphere
View Scheme
参考文献
Jalisatgi, Satish S.; Kulkarni, Vikas S.; Tang, Betty; Houston, Zachary H.; Lee, Mark W.; Hawthorne, M. Frederick
Journal of the American Chemical Society, 2011 , vol. 133, # 32 p. 12382 - 12385
反应条件
silver(l) oxide in dichloromethane
Inert atmosphere;
参考文献
Jalisatgi, Satish S.; Kulkarni, Vikas S.; Tang, Betty; Houston, Zachary H.; Lee, Mark W.; Hawthorne, M. Frederick
Journal of the American Chemical Society, 2011 , vol. 133, # 32 p. 12382 - 12385
