二苯基碘三氟甲烷磺酸盐合成路线 （共 201 条）
反应条件
1: 3-hydroxy-pyridine With potassium tert-butylate in tetrahydrofuran T=0°C; 0.25 h; 2: Diphenyliodonium triflate in tetrahydrofuran T=40°C; 0.833333 h;
参考文献
Jalalian, Nazli; Petersen, Tue B.; Olofsson, Berit
Chemistry--A European Journal, 2012 , vol. 18, # 44 p. 14140 - 14149,10
反应条件
1: 5-bromo-2-hydroxypyrimidine With potassium tert-butylate in N,N-dimethyl-formamide Metallation; 0.25 h; 2: Diphenyliodonium triflate in N,N-dimethyl-formamide T=70°C; Phenylation; 48 h;
参考文献
Jacobsen, Stig Andre; Rodbotten, Synne; Benneche, Tore
Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 22 p. 3265 - 3268
反应条件
1: 4-hydroxyiodobenzene With potassium tert-butylate in tetrahydrofuran T=0°C; 0.25 h; 2: Diphenyliodonium triflate in tetrahydrofuran T=40°C; 0.5 h;
参考文献
Jalalian, Nazli; Petersen, Tue B.; Olofsson, Berit
Chemistry--A European Journal, 2012 , vol. 18, # 44 p. 14140 - 14149,10
反应条件
palladium diacetate in N,N-dimethyl-formamide T=130°C; 0.0333333 h; Schlenk techniqueMicrowave irradiation; regioselective reaction;
参考文献
Li, Jian; Liu, Li; Ding, Dong; Sun, Jiang-Tao
Letters in Organic Chemistry, 2013 , vol. 10, # 1 p. 42 - 46
反应条件
copper(I) bromide in acetonitrile T=80°C; 2 h; Reagent/catalystSolventTemperature;
参考文献
Li, Jian; Liu, Li; Ding, Dong; Sun, Jiang-Tao
Letters in Organic Chemistry, 2013 , vol. 10, # 8 p. 541 - 548
反应条件
copper(l) chloride in acetonitrile T=80°C; 2 h; Reagent/catalyst;
参考文献
Li, Jian; Liu, Li; Ding, Dong; Sun, Jiang-Tao
Letters in Organic Chemistry, 2013 , vol. 10, # 8 p. 541 - 548
反应条件
1: copper; copper(l) chloride / 1,2-dichloro-ethane / 3 h / 20 - 100 °C / Inert atmosphere 2: tris-(dibenzylideneacetone)dipalladium(0); potassium phosphate; [(t-Bu)3PH]BF4 / 1,4-dioxane / 50 °C / Inert atmosphere View Scheme
参考文献
Lin, Hao; Dong, Xicheng; Li, Yuxue; Shen, Qilong; Lu, Long
European Journal of Organic Chemistry, 2012 , # 25 p. 4675 - 4679
反应条件
trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); trifluoroacetic acid T=100°C; 24 h; Overall yield = 67 percent; Overall yield = 28 mg;
参考文献
Storr, Thomas E.; Greaney, Michael F.
Organic Letters, 2013 , vol. 15, # 6 p. 1410 - 1413
反应条件
trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); trifluoroacetic acid
T=100°C; 24 h; Overall yield = 44 percent; Overall yield = 21.7 mg;
参考文献
Storr, Thomas E.; Greaney, Michael F.
Organic Letters, 2013 , vol. 15, # 6 p. 1410 - 1413
反应条件
1: pentan-1-ol With sodium t-butanolate in toluene
T=0 - 20°C; 0.25 h; Inert atmosphere;
2: Diphenyliodonium triflate in toluene
T=0 - 20°C; Inert atmosphere; Reagent/catalystSolventTimeTemperature; chemoselective reaction;
参考文献
Ghosh, Raju; Lindstedt, Erik; Jalalian, Nazli; Olofsson, Berit
ChemistryOpen, 2014 , vol. 3, # 2 p. 54 - 57
