4-(2-乙氧羰基乙基)苯基硼酸合成路线 （共 6 条）
反应条件
1: With bis-(2-hydroxy-ethyl)-amine in isopropyl alcohol T=0°C; 3 h; 2: With sulfuric acid in diethyl ether
参考文献
Zaidlewicz, Marek; Wolan, Andrzej
Journal of Organometallic Chemistry, 2002 , vol. 657, # 1-2 p. 129 - 135
反应条件
hydrogenchloride 24 h; Heating / reflux;
参考文献
WO2004/14859 A2, ;
Page 29 ;
反应条件
1.1: 82 percent / PdCl2(dppf); potassium acetate / dimethylsulfoxide / 27 h / 80 °C 2.1: diethanolamine / propan-2-ol / 3 h / 0 °C 2.2: 76 percent / aq. sulfuric acid / diethyl ether View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 657, # 1-2 p. 129 - 135
反应条件
diisobutylaluminium hydride in tetrahydrofuran; toluene T=-78 - 20°C; Inert atmosphere;
参考文献
Mothana, Sam; Grassot, Jean-Marie; Hall, Dennis G.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 16 p. 2883 - 2887
反应条件
in tetrahydrofuran reaction with aluminium hydride at -78 to 0 °C followed by reaction with Rochelle's salt for 12 h at 0 °C to room temp.; one phase-switch purification used;
参考文献
Mothana, Sam; Grassot, Jean-Marie; Hall, Dennis G.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 16 p. 2883 - 2887
反应条件
sodium hydroxide 3 h; Heating;
参考文献
Zaidlewicz, Marek; Wolan, Andrzej
Journal of Organometallic Chemistry, 2002 , vol. 657, # 1-2 p. 129 - 135
