in toluene
under dry Ar; pentafluorobenzonitrile added via syringe to a soln. of Ge-compd. in dry toluene, refluxed 12h; evapn. (vac.), crystn. (acetonitrile), elem. anal.;
参考文献
Katti, K. V.; Batchelor, R. J.; Einstein, F. W. B.; Cavell, R. G.
Inorganic Chemistry, 1990 , vol. 29, p. 808 - 814
in dichloromethane
ethylselenotrimethylgermane react in CH2Cl2 at -20°C with XeF2 in a molar ratio 1:1 for 20 min, mixt. reacted with PrCCPr at -20°C for 1 h and then at room temp. for 1 h; Me3GeF not isolated (detected by (19)F-NMR);
参考文献
Poleschner, Helmut; Heydenreich, Matthias; Schilde, Uwe
European Journal of Inorganic Chemistry, 2000 , # 6 p. 1307 - 1313
in dichloromethane
ethylselenotrimethylgermane react in CH2Cl2 at -20°C with XeF2 in a molar ratio 1:1 for 20 min, mixt. reacted with PrCCPr at -20°C for 1 h and then at room temp. for 1 h; Me3GeF not isolated (detected by (19)F NMR);
参考文献
Poleschner, Helmut; Heydenreich, Matthias; Schilde, Uwe
European Journal of Inorganic Chemistry, 2000 , # 6 p. 1307 - 1313
Brinkman, Elizabeth A.; Salomon, Karen; Tumas, William; Brauman, John I.
Journal of the American Chemical Society, 1995 , vol. 117, # 17 p. 4905 - 4910
