hydrogenchloride in methanol Kinetics; 8.5 M aq. HCl was added to a methanol soln. of the stannane in a NMR tube, reaction was followed by (1)H NMR spectroscopy for 48 h; rate consts. according to different reaction paths are given; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24
hydrogenchloride in methanol a mixt. of Me6Sn2 and Me3SnCl in MeOH was allowed to react for 70 h until a yellow colour characteristic of the "dimethyl polymer" appeared, one drop of 8.5 M aq. HCl was added, mixt. was kept for 10 min, reaction was followed by (1)H NMR spectroscopy; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24
copper in [3.3.1]nonane freshly precipitated copper; heated in a sealed evacuated ampul at 160°C for 40 h; chromy.;
参考文献
Shcherbakov, V. I.; Grigor'eva, I. K.; D'yachkovskaya, O. S.; Razuvaev, G. A.
Journal of General Chemistry USSR (English Translation), 1985 , vol. 55, p. 91 - 94
Zhurnal Obshchei Khimii, 1985 , vol. 55, p. 107 - 110
in [3.3.1]nonane distannane and freshly pptd. Cu heating in nonane in a sealed tube for 40 h at 160°C, liquid fraction decanting off, solid washing with nonane, solvent removing from combined solns.; Me2SnO isolated as Me2SnCl2;
参考文献
Razuvaev, G.A.; Shcherbakov, V.I.; Grigor'Eva, I.K.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 245 - 252
