cerium(III) chloride in ethanol T=20°C;

cerium(III) chloride in methanol; ethanol T=20°C; 20 h;

1: iodobenzene bis(trifluoroacetate) / aq. ethanol / 1 h / 20 °C 2: CeCl3 / methanol; aq. ethanol / 20 h / 20 °C View Scheme

1: toluene / 4 h / |Reflux; |Dean-Stark 2: sodium tetrahydroborate / methanol / 3 h / 20 °C 3: sodium carbonate / dichloromethane / 6 h / 20 °C 4: hydrogenchloride / 1,4-dioxane / 7 h / |Inert atmosphere; |Reflux 5: N-bromosuccinmide; sulfuric acid / water; tetrahydrofuran / 48 h / 20 °C 6: cerium(III) chloride / water; ethanol / 20 h / 20 °C View Scheme

1: sodium tetrahydroborate / methanol / 3 h / 20 °C 2: sodium carbonate / dichloromethane / 6 h / 20 °C 3: hydrogenchloride / 1,4-dioxane / 7 h / |Inert atmosphere; |Reflux 4: N-bromosuccinmide; sulfuric acid / water; tetrahydrofuran / 48 h / 20 °C 5: cerium(III) chloride / water; ethanol / 20 h / 20 °C View Scheme

1: sodium carbonate / dichloromethane / 6 h / 20 °C 2: hydrogenchloride / 1,4-dioxane / 7 h / |Inert atmosphere; |Reflux 3: N-bromosuccinmide; sulfuric acid / water; tetrahydrofuran / 48 h / 20 °C 4: cerium(III) chloride / water; ethanol / 20 h / 20 °C View Scheme

1: hydrogenchloride / 1,4-dioxane / 7 h / |Inert atmosphere; |Reflux 2: N-bromosuccinmide; sulfuric acid / water; tetrahydrofuran / 48 h / 20 °C 3: cerium(III) chloride / water; ethanol / 20 h / 20 °C View Scheme

1: N-bromosuccinmide; sulfuric acid / water; tetrahydrofuran / 48 h / 20 °C 2: cerium(III) chloride / water; ethanol / 20 h / 20 °C View Scheme

1: hydrogenchloride / 1,4-dioxane / 7 h / |Inert atmosphere; |Reflux; |Darkness 2: potassium tert-butylate / tert-butyl alcohol / 0.5 h / 80 °C 3: N-bromosuccinmide; sulfuric acid / water; tetrahydrofuran / 48 h / 20 °C 4: cerium(III) chloride / water; ethanol / 20 h / 20 °C View Scheme

1: potassium tert-butylate / tert-butyl alcohol / 0.5 h / 80 °C 2: N-bromosuccinmide; sulfuric acid / water; tetrahydrofuran / 48 h / 20 °C 3: cerium(III) chloride / water; ethanol / 20 h / 20 °C View Scheme