1: alkali metal carbonate / N,N-dimethyl-formamide / 3 h / 50 °C 2: sodium nitrite; acetic acid / 16 h / 20 °C 3: sodium hydroxide; water / 1 h / 50 °C View Scheme
in methanol refluxing under N2 for 96 h;; removal of volatiles by distn.; washing of the solid residue with etherin portions; ether extract afforded SnClPh3; elem. anal.;;
purine nucleoside phosphorylase; 2-hydroxyethanethiol; phosphopentomutase in various solvent(s) T=45°C; pH=7; 48 h; Product distribution; Further Variations:pH-valuesTemperaturesreactant and reagent concentrations;
参考文献
Taverna-Porro, Marisa; Bouvier, Leon A.; Pereira, Claudio A.; Montserrat, Javier M.; Iribarren, Adolfo M.
Tetrahedron Letters, 2008 , vol. 49, # 16 p. 2642 - 2645
