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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
66252-14-0
合成路线
（共 9 条）
66252-14-0
→
反应条件
82-05-3
苯并蒽酮
+
6051-98-5
7h-苯并(c)芴-7-酮
反应条件
dichloro bis(acetonitrile) palladium(II); water; silver trifluoroacetate in N,N-dimethyl acetamide; trifluoroacetic acid T=140°C; Heck Reaction; 68 h; GloveboxInert atmosphere; Overall yield = 51 percent; regioselective reaction;
参考文献
Wan, Jung-Chih; Huang, Jun-Min; Jhan, Yu-Huei; Hsieh, Jen-Chieh
Organic Letters, 2013 , vol. 15, # 11 p. 2742 - 2745
66252-14-0
→
反应条件
82-05-3
苯并蒽酮
反应条件
1: IPy2BF4; tetrafluoroboric acid / dichloromethane; diethyl ether / 24 h / -70 °C 2: palladium diacetate; triphenylphosphine; triethylamine / water; N,N-dimethyl-formamide / 22 h / 130 °C / |Inert atmosphere View Scheme
参考文献
Sarkar, Satinath; Jana, Manoranjan; Narender, Tadigoppula
European Journal of Organic Chemistry, 2013 , # 29 p. 6491 - 6495
873-32-5
邻氯苯腈
+
13922-41-3
1-萘硼酸
→
反应条件
66252-14-0
反应条件
potassium fluoride; 18-crown-6 ether; bis-phenanthrylimidazolium chloride; palladium diacetate in tetrahydrofuran T=50°C; Suzuki-Miyaura coupling; 12 h;
参考文献
Song, Chun; Ma, Yudao; Chai, Qiang; Ma, Chanqin; Jiang, Wei; Andrus, Merritt B.
Tetrahedron, 2005 , vol. 61, # 31 p. 7438 - 7446
2042-37-7
2-溴苯腈
+
13922-41-3
1-萘硼酸
→
反应条件
66252-14-0
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium carbonate in ethanol; water; toluene T=80°C; Suzuki-Miyaura cross coupling reaction; Inert atmosphere;
参考文献
Tnay, Ya Lin; Chen, Cheng; Chua, Yi Yuan; Zhang, Line; Chiba, Shunsuke
Organic Letters, 2012 , vol. 14, # 13 p. 3550 - 3553
90-14-2
1-碘萘
+
2042-37-7
2-溴苯腈
→
反应条件
604-53-5
1,1'-联萘
+
66252-14-0
反应条件
tetrabutylammomium bromide; N-ethyl-N,N-diisopropylamine; palladium diacetate in xylene T=130°C; 42 h;
参考文献
Hassan, Jwanro; Hathroubi, Chokri; Gozzi, Christel; Lemaire, Marc
Tetrahedron, 2001 , vol. 57, # 37 p. 7845 - 7855
90-14-2
1-碘萘
+
172732-52-4
2-氰基苯硼酸 1,3-丙二醇酯
→
反应条件
66252-14-0
反应条件
K3PO4; Pd(PPh3)2Cl2 in toluene T=100°C; 12 h; Schlenk techniqueInert atmosphere;
参考文献
Wan, Jung-Chih; Huang, Jun-Min; Jhan, Yu-Huei; Hsieh, Jen-Chieh
Organic Letters, 2013 , vol. 15, # 11 p. 2742 - 2745
→
反应条件
66252-14-0
反应条件
in tetrahydrofuran T=0°C; 2.25 h; Inert atmosphere;
参考文献
Anbarasan, Pazhamalai; Neumann, Helfried; Beller, Matthias
Chemistry - A European Journal, 2010 , vol. 16, # 16 p. 4725 - 4728
138642-62-3
2-氰基苯硼酸
→
反应条件
66252-14-0
反应条件
1: toluene / 2 h / 110 °C 2: Pd(PPh3)2Cl2; K3PO4 / toluene / 12 h / 100 °C / |Schlenk technique; |Inert atmosphere View Scheme
参考文献
Wan, Jung-Chih; Huang, Jun-Min; Jhan, Yu-Huei; Hsieh, Jen-Chieh
Organic Letters, 2013 , vol. 15, # 11 p. 2742 - 2745
66252-14-0
→
反应条件
82-05-3
苯并蒽酮
+
6051-98-5
7h-苯并(c)芴-7-酮
反应条件
dichloro bis(acetonitrile) palladium(II); water; silver trifluoroacetate in N,N-dimethyl acetamide; trifluoroacetic acid T=140°C; Heck Reaction; 68 h; GloveboxInert atmosphere; Overall yield = 51 percent; regioselective reaction;
参考文献
Wan, Jung-Chih; Huang, Jun-Min; Jhan, Yu-Huei; Hsieh, Jen-Chieh
Organic Letters, 2013 , vol. 15, # 11 p. 2742 - 2745
