2,6,6-三甲基环己-2-烯-1-甲醇合成路线 （共 35 条）
反应条件
epoxysulfonyl fluoride in various solvent(s)
T=-82 - -78°C; 0.166667 h;
参考文献
Vlad, P. F.; Ungur, N. D.; Nguen Van Hung; Perutsky, V. B.
Russian Chemical Bulletin, 1995 , vol. 44, # 12 p. 2391 - 2403
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 12 p. 2494 - 2506
反应条件
lithium aluminium tetrahydride in diethyl ether
Heating;
参考文献
Armstrong, Rosemary J.; Weiler, Larry
Canadian Journal of Chemistry, 1983 , vol. 61, p. 2530 - 2539
反应条件
epoxysulfonyl fluoride in various solvent(s)
T=-78°C; 0.0833333 h;
参考文献
Ungur, N. D.; Popa, N. P.; Tuen, Nguen Van; Vlad, P. F.
Chemistry of Natural Compounds, 1993 , vol. 29, # 4 p. 473 - 478
Khimiya Prirodnykh Soedinenii, 1993 , # 4 p. 542 - 548
反应条件
lithium aluminium tetrahydride in diethyl ether
0.5 h; Ambient temperature;
参考文献
Fernandez Mateos; Lopez Barba
Journal of Organic Chemistry, 1995 , vol. 60, # 12 p. 3580 - 3585
反应条件
epoxysulfonyl fluoride in various solvent(s)
T=-82 - -78°C; 0.166667 h;
参考文献
Vlad, P. F.; Ungur, N. D.; Nguen Van Hung; Perutsky, V. B.
Russian Chemical Bulletin, 1995 , vol. 44, # 12 p. 2391 - 2403
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 12 p. 2494 - 2506
反应条件
FeY-zeolite in hexane
T=20°C; 0.5 h;
参考文献
Yu, Wei; Bian, Fengling; Gao, Yuan; Yang, Li; Liu, Zhong-Li
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 1-2 p. 59 - 62
反应条件
NaY-Zeolite in hexane
T=10°C; 48 h;
参考文献
Yu, Wei; Bian, Fengling; Gao, Yuan; Yang, Li; Liu, Zhong-Li
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 1-2 p. 59 - 62
反应条件
zeolite NaY in hexane
T=70°C; 12 h;
参考文献
Tsangarakis, Constantinos; Stratakis, Manolis
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 9 p. 1280 - 1284
反应条件
FeY-zeolite in hexane
T=20°C; 2.5 h; Further byproducts given;
参考文献
Yu, Wei; Bian, Fengling; Gao, Yuan; Yang, Li; Liu, Zhong-Li
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 1-2 p. 59 - 62
反应条件
1: NaH / diethyl ether / 2 h / 0 - 25 °C
2: 75 percent / Mg, Ni(II)-bisacetilacetonate / diethyl ether / 16 h / Heating
3: 1.) SnCl4; 2.) LiAlH4 / 1.) H2O, CH2Cl2, 1 h, 0 deg C; 2.) ether, reflux, 2 h
View Scheme
参考文献
Armstrong, Rosemary J.; Weiler, Larry
Canadian Journal of Chemistry, 1983 , vol. 61, p. 2530 - 2539
