N-烯丙基-n-甲基苯胺合成路线 （共 44 条）
反应条件
titanium(IV) isopropylate; MS 4 Angstroem; palladium diacetate; triphenylphosphine in benzene
T=80°C; Alkylation; N-allylation; 3 h;
参考文献
Yang; Yu; Tsai
Tetrahedron Letters, 2000 , vol. 41, # 36 p. 7097 - 7100
反应条件
triphenylphosphine; potassium iodide; PdI2 in acetonitrile
T=100°C; P=22801.5 Torr; 24 h;
参考文献
Gabriele, Bartolo; Mancuso, Raffaella; Salerno, Giuseppe; Costa, Mirco
Journal of Organic Chemistry, 2007 , vol. 72, # 24 p. 9278 - 9282
反应条件
potassium hydroxide in dimethyl sulfoxide
T=20 - 50°C;
参考文献
Zhang, Lei; Peng, Chen; Zhao, Dan; Wang, Yue; Fu, Hai-Jian; Shen, Qi; Li, Jian-Xin
Chemical Communications, 2012 , vol. 48, # 47 p. 5928 - 5930
反应条件
triphenylphosphine; polystyrene; palladium in toluene
T=65°C; 2 h;
参考文献
Bergbreiter, David E.; Chen, Bushi
Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1238 - 1239
反应条件
copper; Cu(II) perchlorate in diethyl ether
2 h; Ambient temperature;
参考文献
Baruah, Jubaraj B.; Samuelson, Ashoka G.
Tetrahedron, 1991 , vol. 47, # 45 p. 9449 - 9454
反应条件
1: phenyllithium With 3-butyl-1,1-diethyl-1,3-dihydrobenzo[c][1,2]oxasilole in tetrahydrofuran; anhydrous butyl ether
T=-78 - 20°C; Inert atmosphere;
2: N-allyl-N-methyl-O-benzoyl hydroxylamine With copper(l) iodide; dpca in tetrahydrofuran; anhydrous butyl ether
T=20°C; 2 h; Inert atmosphere;
参考文献
Nguyen, Minh H.; Smith, Amos B.
Organic Letters, 2013 , vol. 15, # 18 p. 4872 - 4875
反应条件
1: With tert.-butyl lithium in diethyl ether; pentane
T=-78°C; 1 h;
2: With indium(III) chloride in tetrahydrofuran; diethyl ether; pentane
T=-78°C; 1 h;
3: With water in tetrahydrofuran; diethyl ether; pentane
Heating; Further stages.;
参考文献
Hirashita, Tsunehisa; Hayashi, Ayumi; Tsuji, Makoto; Tanaka, Jiro; Araki, Shuki
Tetrahedron, 2008 , vol. 64, # 11 p. 2642 - 2650
反应条件
lt;phenyl(trimethylsilyl)(polystyrylphenyl)methylgt;palladium(0) in tetrahydrofuran
T=65°C; 6 h;
参考文献
Bergbreiter, David E.; Chen, Bushi; Lynch, Thomas J.
Journal of Organic Chemistry, 1983 , vol. 48, p. 4179 - 4186
反应条件
sodium carbonate in ethanol
14 h; Ambient temperature;
参考文献
Beholz, Lars G.; Stille, John R.
Journal of Organic Chemistry, 1993 , vol. 58, # 19 p. 5095 - 5100
反应条件
1: With tert.-butyl lithium in diethyl ether; pentane
T=-78°C; 1 h;
2: With indium(III) chloride in tetrahydrofuran; diethyl ether; pentane
T=-78°C; 1 h;
3: in tetrahydrofuran; diethyl ether; pentane
T=20°C; 18 h; Irradiation; Further stages.;
参考文献
Hirashita, Tsunehisa; Hayashi, Ayumi; Tsuji, Makoto; Tanaka, Jiro; Araki, Shuki
Tetrahedron, 2008 , vol. 64, # 11 p. 2642 - 2650
