CH3OH in methanol; dichloromethane
byproducts: C10H7(CH2NMe2)-2, SnMe3OMe; a soln. of Sn compd. in CH2Cl2 added to a soln. of Pt complex in CH2Cl2/MeOH, stirred for 1.5 h; concd. (vac.); not isolated, detected by NMR;
参考文献
Amijs, Catelijne H.M.; Kleij, Arjan W.; Van Klink, Gerard P.M.; Spek, Anthony L.; Van Koten, Gerard
Organometallics, 2005 , vol. 24, # 11 p. 2773 - 2779
in tetrahydrofuran; diethyl ether
under N2 atm. to soln. (PtPh(C6H3(CH2NMe2)2)) in THF-Et2O (1:1) HCl was added and stirred for 2 h; ppt. was filtered off and washed with ether; elem. anal.;
参考文献
Ong, Christopher M.; Jennings, Michael C.; Puddephatt, Richard J.
Canadian Journal of Chemistry, 2003 , vol. 81, # 11 p. 1196 - 1205
in dichloromethane
byproducts: Au, NCC6H4(CC)2C6H4CN; addn. of gold compd. to a soln. of platinum compd. in CH2Cl2 at -78 °C, warming to -40 °C, stirring for 20 min; evapn., extn. with pentane and CH2Cl2, evapn.;
参考文献
Back, Stephan; Gossage, Robert A.; Lutz, Martin; Del Rio, Ignacio; Spek, Anthony L.; Lang, Heinrich; van Koten, Gerard
Organometallics, 2000 , vol. 19, # 17 p. 3296 - 3304
in dichloromethane
addn. of Pt-compd. in CH2Cl2 to suspn. of CuCl2 in CH2Cl2 dropwise, stirring mixt. (20 min), pptn.; filtration, concn. of vol. to 2 ml in vac., pptn. by addn. of pentane, filtration, drying in vac.; detn. by (1)H-NMR spectroscopy (product ratio PtCl(NCN)/PtCl3(NCN) 1:2);
参考文献
Koten, Gerard van; Terheijden, Jos; Beek, Johannus A. M. van; Wehman-Ooyevaar, Ingrid C. M.; Muller, Fred; Stam, Caspar H.
Organometallics, 1990 , vol. 9, p. 903 - 912
in ethanol; dichloromethane
addn. of Pt-compd. in CH2Cl2 to soln. of CuCl2 in ethanol dropwise, stirring (30 min); filtration, concn. of vol. to 2 ml in vac., pptn. by addn. of pentane, filtration, drying in vac.; detn. by (1)H-NMR spectroscopy;
参考文献
Koten, Gerard van; Terheijden, Jos; Beek, Johannus A. M. van; Wehman-Ooyevaar, Ingrid C. M.; Muller, Fred; Stam, Caspar H.
Organometallics, 1990 , vol. 9, p. 903 - 912
