碘[三(三氟甲基)]锗烷合成路线 （共 15 条）
反应条件
in dichloromethane at 23°C for 1 h;
参考文献
Journal of the American Chemical Society, , vol. 103, # 11 p. 2995 - 3001
反应条件
120°C, 120 h; in sealed tube; molar ratio based on GeI4: 1.72;
参考文献
Journal of the American Chemical Society, , vol. 100, p. 1722 - 1726
反应条件
in further solvent(s) byproducts: glyme, Cd(CH3)2; Cd compd. added to GeI4 in 1,2-dibromoethane, standing for 1 h, periodically vented to vac.; after volatile germanes recovered, concd., sepd.;
参考文献
Journal of the American Chemical Society, , vol. 103, # 11 p. 2995 - 3001
反应条件
120°C, 120 h; in sealed tube; molar ratio based on GeI4: 2.0;
参考文献
Journal of the American Chemical Society, , vol. 100, p. 1722 - 1726
反应条件
120°C, 120 h; in sealed tube; molar ratio based on GeI4: 0.98;
参考文献
Journal of the American Chemical Society, , vol. 100, p. 1722 - 1726
反应条件
in neat (no solvent) heating mixt. of (CF3)3GeI and small excess of Et3GeH in a sealed and evacuated glass ampoule at 60°C (6 h); vac. condensation in a trap cooled to -30°C, distn. of residue;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 54, p. 83 - 86
Zhurnal Obshchei Khimii, , vol. 54, p. 96 - 100
反应条件
byproducts: AgI; 2-4-fold excess of Ag2Se; heating (vacuum., 110-120°C, 4 d); fractional condensation (dynamic vacuum., 1E-3 Torr, -30,-60,-196°C traps); elem. anal.;
参考文献
Haas, Alois; Kutsch, H.-Juergen
Chemische Berichte, 1988 , vol. 121, p. 803 - 804
反应条件
in neat (no solvent)
byproducts: AgI; condensation of (CF3)3GeI on Ag2S in a closed glass tube, heating on 115°C for 18 h; fractd. condensation; elem. anal.;
参考文献
Eujen, R.; Laufs, F. E.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1988 , vol. 561, p. 82 - 98
反应条件
2-4-fold excess of HgS; heating (vacuum., 110-120°C, 4 d); fractional condensation (dynamic vacuum., 1E-3 Torr, -30,-60,-196°C traps); elem. anal.;
参考文献
Haas, Alois; Kutsch, H.-Juergen
Chemische Berichte, 1988 , vol. 121, p. 803 - 804
反应条件
AgBr
20°C, 24 h; large excess of AgBr;
参考文献
Lagow, R. J.; Eujen, R.; Gerchman, L. L.; Morrison, J. A.
Journal of the American Chemical Society, 1978 , vol. 100, p. 1722 - 1726
