3-三甲基硅烷基丁-3-烯-2-醇合成路线 （共 14 条）
反应条件
2lt;HRh(CO)(PPh3)gt;; 2-trimethylsilyl-1-phenyl-2-propen-1-one in benzene T=105°C; 65 h; in sealed tube; Yield given. Yields of byproduct given;
参考文献
Matsuda, Isamu; Sato, Susumu; Izumi, Yusuke
Tetrahedron Letters, 1983 , vol. 24, # 27 p. 2787 - 2790
反应条件
tert.-butyl lithium in pentane
参考文献
Paquette, Leo A.; Wells, Gregory J.; Horn, Keith A.; Yan, Tu-Hsin
Tetrahedron, 1983 , vol. 39, p. 913 - 924
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
8 h; Ambient temperature;
参考文献
Fleming; Newton; Sabin; Zammattio
Tetrahedron, 1992 , vol. 48, # 37 p. 7793 - 7802
反应条件
in diethyl ether
T=20°C; 15 h;
参考文献
Mesnard; Hanai; Miginiac
Journal of Organometallic Chemistry, 1996 , vol. 519, # 1-2 p. 125 - 135
反应条件
1: 85 percent / NaBH4, CeCl3 / methanol / 1 h / 0 °C
2: 85 percent / n-Bu4NF / tetrahydrofuran / 8 h / Ambient temperature
View Scheme
参考文献
Fleming; Newton; Sabin; Zammattio
Tetrahedron, 1992 , vol. 48, # 37 p. 7793 - 7802
反应条件
2: 85 percent / NaBH4, CeCl3 / methanol / 1 h / 0 °C
3: 85 percent / n-Bu4NF / tetrahydrofuran / 8 h / Ambient temperature
View Scheme
参考文献
Fleming; Newton; Sabin; Zammattio
Tetrahedron, 1992 , vol. 48, # 37 p. 7793 - 7802
反应条件
1: 8.93 g / p-toluenesulfonic acid, H2O / acetone / 1 h / Ambient temperature
2: diethyl ether / 0.5 h / 0 °C
View Scheme
参考文献
Okumoto, Hiroshi; Tsuji, Jiro
Synthetic Communications, 1982 , vol. 12, # 13 p. 1015 - 1020
反应条件
sodium tetrahydroborate; oxygen; rose bengal
1.) MeOH, -5 deg C, irradiation, 5 h, 2.) r.t., overnight; Yield given. Multistep reaction;
参考文献
Adam, Waldemar; Richter, Markus J.
Journal of Organic Chemistry, 1994 , vol. 59, # 12 p. 3341 - 3346
参考文献
Chakrabory; Reddy
Tetrahedron Letters, 1991 , vol. 32, # 5 p. 679 - 682
Title/Abstract Full Text View citing articles Show Details
Matsuda, Isamu; Sato, Susumu; Izumi, Yusuke
Tetrahedron Letters, 1983 , vol. 24, # 27 p. 2787 - 2790
反应条件
1: CrO3 / H2SO4
2: methanol
3: BuLi, tetramethylwenediamine / from -78 deg C to RT.
View Scheme
参考文献
Garratt, Peter J.; Tsotinis, Andrew
Tetrahedron Letters, 1986 , vol. 27, # 24 p. 2761 - 2762
