反应条件
potassium hydroxide; iodine; tetra-n-octylammonium bromide in diethyl ether; benzene
addn. of C6H5CH2CN to mixt. of Cr(CO)3-complex/powd. KOH/TOAB in C6H6 (vigorous stirring), warming (70°C, 5 h), evapn. of solvent (reduced pressure), diln. with aq. HCl, extn. with Et2O, treating with excess I2 (room temp., 3 h); distn. (reduced pressure); identification by GC and NMR; overall yield: 71 percent (50:50 ratio);
参考文献
Baldoli, Clara; Buttero, Paola Del; Licandro, Emanuela; Maiorana, Stefano
Gazzetta Chimica Italiana, 1988 , vol. 118, # 5 p. 409 - 414
