1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prieto, J. Antonio; Larson, Gerald L.
Synthetic Communications, 1980 , vol. 10, # 9 p. 675 - 684
反应条件
1: 1-(trimethylsilyloxy)-1-cyclohexene With diethylzinc in ethylene glycol dimethyl ether; hexane T=0°C; 1 h; 2: perfluoromethyl iodide With RhCl(PPh3)3 in ethylene glycol dimethyl ether; hexane T=-30 - 20°C; Further stages.;
参考文献
Sato, Kazuyuki; Yuki, Takashi; Tarui, Atsushi; Omote, Masaaki; Kumadaki, Itsumaro; Ando, Akira
Tetrahedron Letters, 2008 , vol. 49, # 22 p. 3558 - 3561
反应条件
pyridine in N,N-dimethyl-formamide T=80°C;
参考文献
Umemoto; Ishihara
Tetrahedron Letters, 1990 , vol. 31, # 25 p. 3579 - 3582
反应条件
trimethylsilyl trifluoromethanesulfonate in acetonitrile T=-30 - 20°C; 0.166667 h;
参考文献
Matsugi; Murata; Gotanda; Nambu; Anilkumar; Matsumoto; Kita
Journal of Organic Chemistry, 2001 , vol. 66, # 7 p. 2434 - 2441
反应条件
(i) LDA, THF, (ii) /BRN= 1696885/; Multistep reaction;
参考文献
Seebach,D.; Teschner,M.
Chemische Berichte, 1976 , vol. 109, p. 1601 - 1616
反应条件
potassium fluoride; 2,3,11,12-dicyclohexano-1,4,7,10,13,16-hexaoxacyclo-octadecane in dichloromethane 18 h; Ambient temperature;
参考文献
Ando, Wataru; Tsumaki, Hidetoshi
Tetrahedron Letters, 1982 , vol. 23, # 30 p. 3073 - 3076
反应条件
4-(N,N-dimethlyamino)pyridine in acetonitrile T=20°C; 12 h;
参考文献
Poisson, Thomas; Dalla, Vincent; Papamicael, Cyril; Dupas, Georges; Marsais, Francis; Levacher, Vincent
Synlett, 2007 , # 3 p. 381 - 386
反应条件
bis-(trifluoromethylsulphonyl)amine in dichloromethane T=20°C; 0.333333 h; Inert atmosphere;
参考文献
Mendoza, Oscar; Rossey, Guy; Ghosez, Leon
Tetrahedron Letters, 2010 , vol. 51, # 19 p. 2571 - 2575
反应条件
hydrogenchloride; triethylamine 1) THF; 2) 0 deg C, 1.5 h; 3) benzene, 20 deg C, 16 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Blanco, Luis; Rousseau, Gerard
Bulletin de la Societe Chimique de France, 1985 , # 3 p. 455 - 462
反应条件
1: With triethylamine in hexane T=20°C; Inert atmosphere; 2: With toluene-4-sulfonic acid in hexane T=70°C; Inert atmosphere; regioselective reaction;
参考文献
Schmitt, Daniel C.; Lam, Leighann; Johnson, Jeffrey S.
Organic Letters, 2011 , vol. 13, # 19 p. 5136 - 5139
