1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
1: 84 percent / SnCl4 / CH2Cl2 / 1.5 h / -40 °C
2: 80 percent / tBuOOH, Al2O3 / tetrahydrofuran / 2 h / -78 °C
View Scheme
参考文献
Buckley, Benjamin R.; Fernandez D.-R., Beatriz
Tetrahedron Letters, 2013 , vol. 54, # 8 p. 843 - 846
反应条件
hydrogenchloride; zinc(II) chloride
1.) ethyl acetate, room temp.; Yield given. Multistep reaction;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
zinc(II) chloride in ethyl acetate
Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
hydrogenchloride; water; lt;Pd((R)-p-tol-binap)(H2O)2gt;lt;BF4gt;2
1) DMF, 20 deg C, 43 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Li, Hui-Jing; Tian, Hong-Yu; Wu, Yan-Chao; Chen, Yong-Jun; Liu, Li; Wang, Dong; Li, Chao-Jun
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 9 p. 1247 - 1256
参考文献
Depres, Jean-Pierre; Greene, Andrew E.
Journal of Organic Chemistry, 1980 , vol. 45, p. 2036 - 2037
反应条件
titanium tetrachloride in dichloromethane
-78 deg C, 2 h, then RT, 48 h;
参考文献
Raddo, Pasquale Di; Harvey, Ronald G.
Tetrahedron Letters, 1988 , vol. 29, # 32 p. 3885 - 3886
反应条件
tin(IV) chloride in dichloromethane
T=-20°C; 0.5 h;
参考文献
Ono, Noboru; Yanai, Tetsuya; Kamimura, Akio; Kaji, Aritsune
Journal of the Chemical Society, Chemical Communications, 1986 , # 16 p. 1285 - 1287
反应条件
zinc(II) iodide in dichloromethane
Ambient temperature;
参考文献
Reetz, M. T.; Huettenhain, S.; Huebner, F.
Synthetic Communications, 1981 , vol. 11, # 3 p. 217 - 222
反应条件
zinc(II) iodide in dichloromethane
Ambient temperature;
参考文献
Reetz, M. T.; Huettenhain, S.; Huebner, F.
Synthetic Communications, 1981 , vol. 11, # 3 p. 217 - 222
反应条件
1: SnCl4 / CH2Cl2 / 1 h / -20 °C
2: W-2 Raney nickel / ethanol
View Scheme
参考文献
Hunter; Michael; Walter
Tetrahedron, 1994 , vol. 50, # 31 p. 9377 - 9398
