1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
triethylsilane; 1,1,1,3,3,3-hexamethyl-disilazane; iron(II) sulfate in dichloromethane
T=20°C; 48 h;
参考文献
Yang, Bai-Ling; Tian, Shi-Kai
European Journal of Organic Chemistry, 2007 , # 28 p. 4646 - 4650
反应条件
zinc(II) chloride in ethyl acetate
Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
trimethylsilyl iodide in acetonitrile
T=70°C; 1 h;
参考文献
Kozyukov, V. P.; Kozyukov, Vik. P.; Mironov, V. F.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 2 p. 467 - 468,414 - 415
反应条件
bis-(trifluoromethylsulphonyl)amine in dichloromethane
T=-78°C; Mukaiyama cross-aldol reaction; 2 h;
参考文献
Cossy; Lutz; Alauze; Meyer
Synlett, 2002 , # 1 p. 45 - 48
反应条件
titanium tetrachloride in dichloromethane
1.) -78 deg C, 1.5 h, 2.) -78 deg C to r.t.;
参考文献
Braga, Antonio L.; Dornelles, Luciano; Silveira, Claudio C.; Wessjohann, Ludger A.
Synthesis, 1999 , # 4 p. 562 - 564
反应条件
zinc(II) chloride in ethyl acetate
Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
iodosylbenzene; boron trifluoride diethyl etherate
T=-70°C; 3.5 h;
参考文献
Moriarty, Robert M.; Prakash, Om; Duncan, Michael P.; Vaid, Radhe K.; Mussallam, Hikmat A.
Journal of Organic Chemistry, 1987 , vol. 52, # 1 p. 150 - 153
反应条件
1: I2 / CH2Cl2
2: CH2Cl2
3: Et3N*HF / CH2Cl2 / 2 h
View Scheme
参考文献
Rubottom, George M.; Mott, Robert C.; Juve, Henrik D.
Journal of Organic Chemistry, 1981 , vol. 46, # 13 p. 2717 - 2721
反应条件
1: 84 percent / ZnBr2 / CH2Cl2 / 16 h / 20 °C
2: 92 percent / W-2 Raney nickel / acetone; ethanol / 2 h / 20 °C
View Scheme
参考文献
Fleming, Ian; Patel, Shailesh K.; Urch, Christopher J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 115 - 124
反应条件
nickel
Yield given. Multistep reaction;
参考文献
Fleming, Ian
Bulletin de la Societe Chimique de France, 1981 , vol. 2, # 1-2 p. 7 - 13
