1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
1: 97 percent / Na2CO3 / CH2Cl2 / 20 h / Ambient temperature
2: 26 percent / Fe3(CO)12 / toluene / 3 h / 110 °C
View Scheme
参考文献
Nakanishi, Saburo; Otsuji, Yoshio; Itoh, Keiji; Hayashi, Nobuaki
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 12 p. 3595 - 3600
反应条件
diethylzinc in benzene
T=20°C; 20 h;
参考文献
Ryu, Ilhyong; Aya, Tomoyuki; Otani, Shoji; Murai, Shinji; Sonoda, Noboru
Journal of Organometallic Chemistry, 1987 , vol. 321, p. 279 - 290
反应条件
diethylzinc in pentane
T=15°C; 20 h; Heating; Yields of byproduct given;
参考文献
Ryu, Ilhyong; Aya, Tomoyuki; Otani, Shoji; Murai, Shinji; Sonoda, Noboru
Journal of Organometallic Chemistry, 1987 , vol. 321, p. 279 - 290
反应条件
in toluene
1 h; Heating;
参考文献
Sparey, Tim J.; Harrison, Timothy
Tetrahedron Letters, 1998 , vol. 39, # 32 p. 5873 - 5874
反应条件
lithium aluminium tetrahydride; titanium tetrachloride in tetrahydrofuran
T=0°C; 0.5 h;
参考文献
Mitani, Michiharu; Kobayashi, Yoshinori
Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 1 p. 284 - 286
反应条件
hydrogenchloride; triethylamine
1) THF; 2) 0 deg C, 1.5 h; 3) benzene, 20 deg C, 16 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Blanco, Luis; Rousseau, Gerard
Bulletin de la Societe Chimique de France, 1985 , # 3 p. 455 - 462
反应条件
(i), (ii) aq. HCl; Multistep reaction;
参考文献
Macdonald,T.L.
Journal of Organic Chemistry, 1978 , vol. 43, # 21 p. 4241 - 4244
反应条件
1: 72 percent / SnCl4 / -35 - -30 °C
2: 77 percent / pyridine, methyl chlorosulfite / tetrahydrofuran / 36 h
View Scheme
参考文献
Ishihara, Takashi; Shinjo, Hiroshi; Inoue, Yoshihisa; Ando, Teiichi
Journal of Fluorine Chemistry, 1983 , vol. 22, p. 1 - 20
反应条件
(i) CH2Cl2, AlCl3, (ii) H2O; Multistep reaction;
参考文献
Miyashita,M. et al.
Journal of the American Chemical Society, 1976 , vol. 98, p. 4679 - 4681
反应条件
carbon dioxide in dichloromethane; dimethyl sulfoxide; acetonitrile
T=-40 - 20°C;
参考文献
Iwama, Tetsuo; Birman, Vladimir B.; Kozmin, Sergey A.; Rawal, Viresh H.
Organic Letters, 1999 , vol. 1, # 4 p. 673 - 676
