1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
tri-tert-butyl phosphine; tri-n-butyltin fluoride; tris(dibenzylideneacetone)dipalladium (0) in benzene
3.5 h; Heating;
参考文献
Iwama, Tetsuo; Rawal, Viresh H.
Organic Letters, 2006 , vol. 8, # 25 p. 5725 - 5728
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate; bromine
1.) THF, acetonitrile, -78 deg C, overnight; 2.) THF, acetonitrile, cyclohexane, 10 min, -78 deg C; to RT; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
RajanBabu, T. V.; Reddy, G. S.; Fukunaga, Tadamichi
Journal of the American Chemical Society, 1985 , vol. 107, # 19 p. 5473 - 5483
反应条件
potassium tert-butylate
参考文献
Katritzky, Alan R.; Hayden, Amy E.; Kirichenko, Kostyantyn; Pelphrey, Phillip; Ji, Yu
Journal of Organic Chemistry, 2004 , vol. 69, # 15 p. 5108 - 5111
反应条件
in dichloromethane
T=0°C; 3 h;
参考文献
Zhdankin, Viktor V.; Kuehl, Chris J.; Simonsen, Angela J.
Journal of Organic Chemistry, 1996 , vol. 61, # 23 p. 8272 - 8276
反应条件
in dichloromethane
2 h; Ambient temperature;
参考文献
Moriarty, Robert M.; Penmasta, Raju; Awasthi, Alok K.; Epa, W. Ruwan; Prakash, Indra
Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1101 - 1104
反应条件
in dichloromethane
T=0°C; 3 h;
参考文献
Zhdankin, Viktor V.; Kuehl, Chris J.; Simonsen, Angela J.
Tetrahedron Letters, 1995 , vol. 36, # 13 p. 2203 - 2206
反应条件
1: 88 percent / TiCl4 / CH2Cl2 / 2 h / -23 °C
2: 1) NaIO4 / 1) MeOH, room temp., 16 h; 2) CCl4, CHCl3, 70 deg C, 15 h
View Scheme
参考文献
Fleming, Ian; Iqbal, Javed
Tetrahedron Letters, 1983 , vol. 24, # 3 p. 327 - 328
反应条件
1: 1.) MeLi / 1.) DME, RT, 20 min, 2.) DME, 1.5 h
2: 54 percent / 60percent aq. HClO4 / CCl4 / 3 h / Ambient temperature
View Scheme
参考文献
Takahashi, Tamiko; Nakao, Naoki; Koizumi, Toru
Tetrahedron Asymmetry, 1997 , vol. 8, # 19 p. 3293 - 3308
反应条件
in chloroform-d1
at 35°C;
参考文献
Nakamura, Eiichi; Kuwajima, Isao
Chemistry Letters, 1983 , p. 59 - 62
反应条件
1: oxirane; 1-(trimethylsilyloxy)-1-cyclohexene With titanium tetrachloride in dichloromethane
T=-78 - -60°C; Mukaiyama reaction;
2: methanol With toluene-4-sulfonic acid in dichloromethane
T=20°C; 2 h;
参考文献
Lalic, Gojko; Petrovski, Zeljko; Galonic, Danica; Matovic, Radomir; Saicic, Radomir N
Tetrahedron, 2001 , vol. 57, # 3 p. 583 - 591
