1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
PPh3 gold(I) chloro complex; silver perchlorate in benzene
T=80°C; 2 h;
参考文献
Aikawa, Haruo; Kaneko, Tetsuro; Asao, Naoki; Yamamoto, Yoshinori
Beilstein Journal of Organic Chemistry, 2011 , vol. 7, art. no. 76, p. 648 - 652
反应条件
1: titanium tetrachloride / CH2Cl2 / 2 h / -78 °C
2: 0.42 g / titanium tetrachloride / CH2Cl2 / 1.) -78 deg C, 2 h, 2.) -23 deg C, 4 h
View Scheme
参考文献
Chan, Tak-Hang; Brownbridge, Peter
Journal of the American Chemical Society, 1980 , vol. 102, # 10 p. 3534 - 3538
反应条件
1: With potassium carbonate; 3-chloro-benzenecarboperoxoic acid in dichloromethane; water
T=0°C; 1 h;
2: With silica gel in Petroleum ether
T=20°C; 6 h;
参考文献
Novikov, Yehor Y.; Sampson, Paul
Organic Letters, 2003 , vol. 5, # 13 p. 2263 - 2266
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Friedrich, Edgar; Lutz, Werner
Chemische Berichte, 1980 , vol. 113, # 4 p. 1245 - 1263
反应条件
1: tris-(dibenzylideneacetone)dipalladium(0); tri-n-butyltin fluoride; triethylamine; [(t-Bu)3PH]BF4 / benzene / 24 h / 80 °C / Inert atmosphere
2: pyridine; sodium iodide / hexane; acetonitrile / 20 h / 20 °C
View Scheme
参考文献
Beck, Elizabeth M.; Hyde, Alan M.; Jacobsen, Eric N.
Organic Letters, 2011 , vol. 13, # 16 p. 4260 - 4263
反应条件
Ni(PCy3)2Cl2 in toluene
T=80°C; Kumada-Tamao-Corriu coupling; 10 h; Inert atmosphere;
参考文献
Zhao, Fei; Yu, Da-Gang; Zhu, Ru-Yi; Xi, Zhenfeng; Shi, Zhang-Jie
Chemistry Letters, 2011 , vol. 40, # 9 p. 1001 - 1003
反应条件
pyridine in acetonitrile
0.7 h; Ambient temperature;
参考文献
Umemoto, Teruo; Kuriu, Yuriko; Nakayama, Shin-ichi; Miyano, Osamu
Tetrahedron Letters, 1982 , vol. 23, # 14 p. 1471 - 1474
反应条件
2,6-dimethylpyridine; triethyl borane in hexane
T=25°C; 8 h; Product distribution;
参考文献
Miura, Katsukiyo; Takeyama, Yoshihiro; Oshima, Koichiro; Utimoto, Kiitiro
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1542 - 1553
反应条件
2,6-dimethylpyridine; triethyl borane in hexane
Yields of byproduct given;
参考文献
Miura, Katsukiyo; Takeyama, Yoshihiro; Oshima, Koichiro; Utimoto, Kiitiro
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1542 - 1553
反应条件
2,6-dimethylpyridine; hydrogenchloride; triethyl borane
1) hexane, 25 deg C, 6 h, 2) THF, 10 min; Yield given. Multistep reaction;
参考文献
Miura, Katsukiyo; Taniguchi, Masahiko; Nozaki, Kyoko; Oshima, Koichiro; Utimoto, Kiitiro
Tetrahedron Letters, 1990 , vol. 31, # 44 p. 6391 - 6394
