1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
diethylzinc in pentane
T=15°C; 20 h; Heating; Yields of byproduct given;
参考文献
Ryu, Ilhyong; Aya, Tomoyuki; Otani, Shoji; Murai, Shinji; Sonoda, Noboru
Journal of Organometallic Chemistry, 1987 , vol. 321, p. 279 - 290
参考文献
Murai,S. et al.
Journal of Organic Chemistry, 1974 , vol. 39, # 6 p. 858 - 859
反应条件
zinc/copper couple
T=70°C; Simmons-Smith Cyclopropanation; 2 h; TemperatureSolventTime;
参考文献
Fujii, Kanami; Shiine, Kodai; Misaki, Tomonori; Sugimura, Takashi
Applied Organometallic Chemistry, 2013 , vol. 27, # 2 p. 69 - 72
反应条件
tri-tert-butyl phosphine; tri-n-butyltin fluoride; tris(dibenzylideneacetone)dipalladium (0) in benzene
8 h; Heating;
参考文献
Iwama, Tetsuo; Rawal, Viresh H.
Organic Letters, 2006 , vol. 8, # 25 p. 5725 - 5728
反应条件
tri-tert-butyl phosphine; tri-n-butyltin fluoride; tris(dibenzylideneacetone)dipalladium (0) in benzene
8 h; Heating;
参考文献
Iwama, Tetsuo; Rawal, Viresh H.
Organic Letters, 2006 , vol. 8, # 25 p. 5725 - 5728
反应条件
tri-tert-butyl phosphine; tri-n-butyltin fluoride; tris(dibenzylideneacetone)dipalladium (0) in benzene
5 h; Heating;
参考文献
Iwama, Tetsuo; Rawal, Viresh H.
Organic Letters, 2006 , vol. 8, # 25 p. 5725 - 5728
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate; bromine
1.) THF, acetonitrile, -78 deg C, overnight; 2.) THF, acetonitrile, cyclohexane, 10 min, -78 deg C; to RT; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
RajanBabu, T. V.; Reddy, G. S.; Fukunaga, Tadamichi
Journal of the American Chemical Society, 1985 , vol. 107, # 19 p. 5473 - 5483
反应条件
tri-tert-butyl phosphine; tri-n-butyltin fluoride; tris(dibenzylideneacetone)dipalladium (0) in benzene
21 h; Heating;
参考文献
Iwama, Tetsuo; Rawal, Viresh H.
Organic Letters, 2006 , vol. 8, # 25 p. 5725 - 5728
反应条件
tri-tert-butyl phosphine; tri-n-butyltin fluoride; tris(dibenzylideneacetone)dipalladium (0) in benzene
20 h; Heating;
参考文献
Iwama, Tetsuo; Rawal, Viresh H.
Organic Letters, 2006 , vol. 8, # 25 p. 5725 - 5728
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tri-n-butyltin fluoride; triethylamine; [(t-Bu)3PH]BF4 in benzene
T=80°C; 24 h; Inert atmosphere;
参考文献
Beck, Elizabeth M.; Hyde, Alan M.; Jacobsen, Eric N.
Organic Letters, 2011 , vol. 13, # 16 p. 4260 - 4263
