双环[3.3.1]壬-3-烯合成路线 （共 22 条）
反应条件
1: (i) TsCl, Py, (ii) /BRN= 4725512/, EtOH
2: aq. KOH
3: xylene / Heating
4: SOCl2, Py / benzene
5: AlCl3 / 1,2-dichloro-ethane
6: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Marvell,E.N. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 391 - 396
反应条件
1: SOCl2, Py / benzene
2: AlCl3 / 1,2-dichloro-ethane
3: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Marvell,E.N. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 391 - 396
反应条件
1: CrO3, aq. H2SO4 / acetone
2: SOCl2, Py / benzene
3: AlCl3 / 1,2-dichloro-ethane
4: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Marvell,E.N. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 391 - 396
反应条件
1: xylene / Heating
2: SOCl2, Py / benzene
3: AlCl3 / 1,2-dichloro-ethane
4: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Marvell,E.N. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 391 - 396
反应条件
1: aq. KOH
2: xylene / Heating
3: SOCl2, Py / benzene
4: AlCl3 / 1,2-dichloro-ethane
5: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Marvell,E.N. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 391 - 396
反应条件
methanol; ethanol; dihydrogen peroxide
Erhitzen des Reaktionsprodukts bis auf 145grad;
参考文献
Schaefer,J.P. et al.
Journal of Organic Chemistry, 1967 , vol. 32, p. 1372 - 1378
反应条件
2,6-dimethylpyridine
T=50°C; Elimination; solvolysis; Product distributionKineticsThermodynamic data; Further Variations:Temperatures;
参考文献
Okazaki, Takao; Terakawa, Eiichi; Kitagawa, Toshikazu; Takeuchi, Ken'ichi
Journal of Organic Chemistry, 2000 , vol. 65, # 6 p. 1680 - 1684
反应条件
ethanol
T=40°C; solvolysis; MechanismRate constant;
参考文献
Grob, Cyril A.; Waldner, Adrian
Tetrahedron Letters, 1981 , vol. 22, # 34 p. 3235 - 3238
反应条件
2,6-dimethylpyridine
T=40°C; Elimination; solvolysis; Product distributionKineticsThermodynamic data; Further Variations:Temperatures;
参考文献
Okazaki, Takao; Terakawa, Eiichi; Kitagawa, Toshikazu; Takeuchi, Ken'ichi
Journal of Organic Chemistry, 2000 , vol. 65, # 6 p. 1680 - 1684
参考文献
Gerlach,H. et al.
Journal of the Chemical Society, Chemical Communications, 1972 , p. 1215 - 1216
