3-甲基-4-苯基-1-丁烯合成路线 （共 61 条）
反应条件
triphenylphosphine; isopropyl alcohol; Wilkinson's catalyst in tetrahydrofuran
T=25°C; 1 h;
参考文献
Lebel, Helene; Paquet, Valerie
Organic letters, 2002 , vol. 4, # 10 p. 1671 - 1674
反应条件
formic acid; triethylamine; palladium on activated charcoal
T=25°C; 72 h;
参考文献
Weir, John R.; Patel, Babu A.; Heck, Richard F.
Journal of Organic Chemistry, 1980 , vol. 45, # 24 p. 4926 - 4931
反应条件
Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran
T=25°C; 0.5 h; Inert atmosphere; regioselective reaction;
参考文献
Rao Volla, Chandra M.; Dubbaka, Srinivas Reddy; Vogel, Pierre
Tetrahedron, 2009 , vol. 65, # 2 p. 504 - 511
反应条件
potassium tert-butylate; C29H30ClNOP2Ru(1+) in acetone
T=60°C; 1 h; Inert atmosphere; Product distribution / selectivity;
参考文献
TAKASAGO INTERNATIONAL CORPORATION; TOUGE, Taichiro; AOKI, Kunie; NARA, Hideki; KURIYAMA, Wataru
Patent: WO2012/144650 A1, 2012 ;
Location in patent: Page/Page column 46-48 ;
反应条件
tri-n-butyl-tin hydride; tetrakis(triphenylphosphine) palladium(0)
T=25°C; 10 h;
参考文献
Taniguchi, Masahiko; Takeyama, Yoshihiro; Fugami, Keigo; Oshima, Koichiro; Utimoto, Kiitiro
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2593 - 2595
反应条件
toluene-4-sulfonic acid in toluene
5 h; Heating; Yield given. Yields of byproduct given;
参考文献
Von Doering; Benkhoff, Johannes; Carleton, Peter Smart; Pagnotta, Marco
Journal of the American Chemical Society, 1997 , vol. 119, # 45 p. 10947 - 10955
反应条件
chloro-trimethyl-silane; sodium iodide in water
T=0°C; 1 h;
参考文献
Oonishi, Yoshihiro; Mori, Miwako; Sato, Yoshihiro
Synthesis, 2007 , # 15 p. 2323 - 2336
反应条件
1: 4-phenyl-1,3-bis(phenylthio)but-1-ene With Cp2Ti[P(OEt)3]2 in tetrahydrofuran
T=0°C; desulfurization; 0.166667 h;
2: 2-chloro-2-methyl-4-phenylbutane in tetrahydrofuran
Alkylation; 2 h;
参考文献
Takeda, Takeshi; Nozaki, Naoki; Saeki, Naoko; Fujiwara, Tooru
Tetrahedron Letters, 1999 , vol. 40, # 29 p. 5353 - 5356
反应条件
1: Mg / Grignard reaction
2: D3PO4 / 3 h / 230 - 240 °C
View Scheme
参考文献
Sakhabutdinov, A. G.; Usmanova, A. G.; Frolov, P. A.; Kushnarev, D. F.; Schmidt, F. K.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 8 p. 1452 - 1455
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 8 p. 1610 - 1614
反应条件
magnesium in diethyl ether
参考文献
Warrick,P.; Saunders,W.H.
Journal of the American Chemical Society, 1962 , vol. 84, p. 4095 - 4100
