3-甲基-4-苯基-1-丁烯合成路线 （共 61 条）
反应条件
diphenyl diselenide; potassium carbonate; hydrazine hydrate in dimethyl sulfoxide
Elimination; Title compound not separated from byproducts.;
参考文献
Vasil'ev, Andrei; Engman, Lars
Journal of Organic Chemistry, 2000 , vol. 65, # 7 p. 2151 - 2162
反应条件
1: NaIO4 / 1) acetone, water. 0 deg C, 3 h, 2) r.t., 12 h
2: nBuLi, TMEDA / hexane / 24 h / 19 °C / further reagents, solvents, and temperatures; The factors governing the competitions between 1,2- and 1,3-eliminations was studied.
View Scheme
参考文献
Babin, D.; Fourneron, J. D.; Harwood, L. M.; Julia, M.
Tetrahedron, 1981 , vol. 37, p. 325 - 332
反应条件
1: With triethylamine tris(hydrogen fluoride); triethylamine in ethyl acetate
T=5 - 23°C; 0.0833333 h;
2: With TFFH in ethyl acetate
T=60°C; 16 h;
参考文献
Bellavance, Gabriel; Dube, Pascal; Nguyen, Bao
Synlett, 2012 , # 4 p. 569 - 572
反应条件
iron (III) acetylacetonate; N,N,N',N,-tetramethylethylenediamine; CPME in diethyl ether
T=20°C; 18 h; Inert atmosphere;
参考文献
Denmark, Scott E.; Cresswell, Alexander J.
Journal of Organic Chemistry, 2013 , vol. 78, # 24 p. 12593 - 12628
反应条件
magnesium in diethyl ether
参考文献
Sneeden,R.P.A.; Zeiss,H.H.
Journal of Organometallic Chemistry, 1971 , vol. 26, p. 101 - 113
反应条件
tetraethylammonium p-toluenesulfonate in N,N-dimethyl-formamide
(electrochemical reduction);
参考文献
Shono,T. et al.
Tetrahedron Letters, 1978 , # 31 p. 2807 - 2810
反应条件
trimethylsilylazide; tetrabutyl ammonium fluoride in tetrahydrofuran
17 h; Ambient temperature;
参考文献
Ito; Koyakumaru; Ohta; Takaya
Synthesis, 1995 , # 4 p. 376 - 378
反应条件
lithium aluminium tetrahydride; copper dichloride in tetrahydrofuran
参考文献
Nakai,T. et al.
Chemistry Letters, 1975 , p. 249 - 252
反应条件
Fe(acetylacetonate)2 in tetrahydrofuran; diethyl ether
T=15°C; 4.5 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Zubritskii, L. M.; Romashchenkova, N. D.; Petrov, A. A.
Journal of Organic Chemistry USSR (English Translation), 1983 , p. 2157 - 2167
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 12 p. 2465 - 2477
反应条件
1: (i) Li, (ii) /BRN= 385801/
2: LiAlH4, CuCl2 / tetrahydrofuran
View Scheme
参考文献
Nakai,T. et al.
Chemistry Letters, 1975 , p. 249 - 252
