3-甲基-4-苯基-1-丁烯合成路线 （共 61 条）
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane
T=19°C; 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Babin, D.; Fourneron, J. D.; Harwood, L. M.; Julia, M.
Tetrahedron, 1981 , vol. 37, p. 325 - 332
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane
T=19°C; 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Babin, D.; Fourneron, J. D.; Harwood, L. M.; Julia, M.
Tetrahedron, 1981 , vol. 37, p. 325 - 332
反应条件
Yield given. Multistep reaction;
参考文献
Torisawa, Yasuhiro; Shibasaki, Masakatsu; Ikegami, Shiro
Tetrahedron Letters, 1981 , vol. 22, # 25 p. 2397 - 2400
反应条件
in cyclohexane
1 h; Ambient temperatureIrradiation; Yield given. Yields of byproduct given;
参考文献
Hixson, Stephen S.; Gallucci, Charles R.
Journal of Organic Chemistry, 1988 , vol. 53, # 12 p. 2711 - 2713
反应条件
phosphoric acid, fully deuterated
T=230 - 240°C; 3 h; Product distributionMechanism;
参考文献
Sakhabutdinov, A. G.; Usmanova, A. G.; Frolov, P. A.; Kushnarev, D. F.; Schmidt, F. K.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 8 p. 1452 - 1455
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 8 p. 1610 - 1614
反应条件
Fe(acetylacetonate)2 in tetrahydrofuran; diethyl ether
T=5 - 15°C; 4.5 h; other temperature; other catalyst; other products; Product distributionMechanism;
参考文献
Zubritskii, L. M.; Romashchenkova, N. D.; Petrov, A. A.
Journal of Organic Chemistry USSR (English Translation), 1983 , p. 2157 - 2167
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 12 p. 2465 - 2477
反应条件
T=230.1°C; Yield given. Yields of byproduct given;
参考文献
Gonzalez, Neil; Martin, Ignacio; Chuchani, Gabriel
Journal of Physical Chemistry, 1985 , vol. 89, # 7 p. 1314 - 1318
反应条件
in tert-butyl alcohol
Irradiationphotolysis of alkyl aryl sulfoxides; homolytic cleavage; possible reaction pathways; proposed mechanism; thermal degradation (t-BuOH, 80 deg C); comparison of olefinic products from photolysis and thermolysis; regioselectivity of alkene products; Product distributionQuantum yield;
参考文献
Guo, Yushen; Jenks, William S.
Journal of Organic Chemistry, 1997 , vol. 62, # 4 p. 857 - 864
反应条件
1: 21.8 g / m-chloroperbenzoic acid / CH2Cl2 / Heating
2: 24 percent / lithium diethylamide
3: 32 percent / pyridine / CH2Cl2 / 2 h
4: 76 percent / sodium iodide / acetone / 0.5 h / Ambient temperature
5: 28 percent Chromat. / potassium carbonate / acetonitrile / 20 h / 20 °C / Irradiation
View Scheme
参考文献
Charlton, James Leslie; Williams, Gaynor Jane; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 1271 - 1274
反应条件
hydrogen; (CO)4(PEtPh2)W(μ-PPh2)Rh(CO)(PPh3) in toluene
T=50°C; P=760 Torr; 50 h;
参考文献
Yamane, Motoki; Yukimura, Noriaki; Ishiai, Hiroshi; Narasaka, Koichi
Chemistry Letters, 2006 , vol. 35, # 5 p. 540 - 541
