(R)-1,2-环氧癸烷合成路线 （共 21 条）
反应条件
potassium carbonate in methanol
T=0 - 20°C;
参考文献
Matsumoto, Kazutsugu; Usuda, Kazumasa; Okabe, Hirokazu; Hashimoto, Manabu; Shimada, Yasutaka
Tetrahedron Asymmetry, 2013 , vol. 24, # 2-3 p. 108 - 115
反应条件
air; (R,R)-(salen)Co(II)complex; acetic acid; water in diethyl ether
T=20°C; 72 h;
参考文献
Trost, Barry M.; Machacek, Michelle R.; Faulk, Brian D.
Journal of the American Chemical Society, 2006 , vol. 128, # 20 p. 6745 - 6754
反应条件
sodium hydroxide in tetrahydrofuran
T=20°C; Cyclization; 3 h;
参考文献
Nakayama, Yuji; Kumar, G. Biju; Kobayashi, Yuichi
Journal of Organic Chemistry, 2000 , vol. 65, # 3 p. 707 - 715
反应条件
potassium carbonate in ethanol
1 h;
参考文献
Bonini, Carlo; Federici, Chiara; Rossi, Leucio; Righi, Giuliana
Journal of Organic Chemistry, 1995 , vol. 60, # 15 p. 4803 - 4812
参考文献
Shi, Yian
Patent: US6348608 B1, 2002 ;
Location in patent: Page column 33 ;
反应条件
sodium hydride; 1-(toluene-p-sulphonyl)imidazole in tetrahydrofuran; N,N-dimethyl-formamide
T=0 - 25°C; 1.) 1 h, 2.) 0.5 h;
参考文献
Eisenberg, Christina; Knochel, Paul
Journal of Organic Chemistry, 1994 , vol. 59, # 14 p. 3760 - 3761
反应条件
sodium methylate in methanol
Ambient temperaturee.e. 96percent; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Oppolzer, Wolfgang; Dudfield, Philip
Tetrahedron Letters, 1985 , vol. 26, # 41 p. 5037 - 5040
反应条件
1: 98 percent / LiI, Amberlyst 15 / acetonitrile / Ambient temperature
2: 86 percent / Bu3SnH
3: 96 percent / K2CO3 / ethanol / 1 h
View Scheme
参考文献
Bonini, Carlo; Federici, Chiara; Rossi, Leucio; Righi, Giuliana
Journal of Organic Chemistry, 1995 , vol. 60, # 15 p. 4803 - 4812
反应条件
1: 86 percent / Bu3SnH
2: 96 percent / K2CO3 / ethanol / 1 h
View Scheme
参考文献
Bonini, Carlo; Federici, Chiara; Rossi, Leucio; Righi, Giuliana
Journal of Organic Chemistry, 1995 , vol. 60, # 15 p. 4803 - 4812
反应条件
Oxonereg;; C6H10O6(C3H4)2; tetra(n-butyl)ammonium hydrogensulfate; (ethylenedinitrilo)tetraacetic acid disodium salt; sodium hydrogencarbonate in water; acetonitrile
T=-10°C; 1.5 h; other reaction time, solvent, reagent; Product distribution;
参考文献
Wang, Zhi-Xian; Tu, Yong; Frohn, Michael; Zhang, Jian-Rong; Shi, Yian
Journal of the American Chemical Society, 1997 , vol. 119, # 46 p. 11224 - 11235
