反应条件
1: aq. KIO4, p-TsOH / acetone / Ambient temperature
2: 1.) t-BuOK / 1.) THF, 1.5 h, 2.) THF, from -5 to 0 deg C, 1.5 h
3: H2, HCl/MeOH / 5percent Pd/C / 2585.7 Torr
4: 81 percent / aq. KMnO4, AcOH / acetone / Ambient temperature
View Scheme
参考文献
Breitenbach, Ralph; Chiu, Charles K.-F.; Massett, Stephen S.; Meltz, Morgan; Murtiashaw, C. William; Pezzullo, Susan L.; Staigers, Thomas
Tetrahedron Asymmetry, 1996 , vol. 7, # 2 p. 435 - 442
