3',4'-亚甲二氧基异苯丁酮合成路线 （共 3 条）
反应条件
(NH4)2S2O8; [{(η5-C5Me5)RhCl}2(μ-Cl)2] in water
T=110°C; 12 h; Inert atmosphereSealed tube;
参考文献
Li, Yang; Xue, Dong; Lu, Wei; Wang, Chao; Liu, Zhao-Tie; Xiao, Jianliang
Organic Letters, 2014 , vol. 16, # 1 p. 66 - 69
反应条件
[(η5-C5Me5)2Rh2(μ-Cl)2Cl2]; oxygen; caesium carbonate in methanol
T=65°C; 48 h; Sealed tube;
参考文献
Chan, Louis K. M.; Poole, Darren L.; Shen, Di; Healy, Mark P.; Donohoe, Timothy J.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 3 p. 761 - 765
Angew. Chem., 2014 , vol. 126, # 3 p. 908
反应条件
1: [{(η5-C5Me5)RhCl}2(μ-Cl)2]; (NH4)2S2O8 / water / 3 h / 110 °C / |Inert atmosphere; |Sealed tube
2: [{(η5-C5Me5)RhCl}2(μ-Cl)2]; (NH4)2S2O8 / water / 12 h / 110 °C / |Inert atmosphere; |Sealed tube
View Scheme
参考文献
Li, Yang; Xue, Dong; Lu, Wei; Wang, Chao; Liu, Zhao-Tie; Xiao, Jianliang
Organic Letters, 2014 , vol. 16, # 1 p. 66 - 69
