1: With hydrogen bromide in water T=0°C; 2: With sodium nitrite in water T=-10°C; 3: in water; toluene T=20°C; 0.5 h;

hydrogenchloride

暂无反应条件数据

1.1: aq. sodium hydroxide; sodium carbonate / 0 - 23 °C 2.1: phosphorus pentachloride / CH2Cl2 / -10 - 20 °C 3.1: aluminum chloride / CH2Cl2 / 22 - 28 °C 3.2: aq. HCl / CH2Cl2 / -5 - 1 °C 4.1: Red-Al; sodium bis(2-methoxyethoxy)aluminum hydride / toluene; tetrahydrofuran / -10 - 0 °C 5.1: pyridine / CH2Cl2 / -5 - 0 °C 6.1: nitric acid; trifluoroacetic acid; trifluoroacetic anhydride / CH2Cl2 / -35 - -30 °C 7.1: NaOH; methanol / 23 °C 8.1: acetic acid; perchloric acid; hydrogen / Pd/C / 15.5 h / 2172.08 - 2585.81 Torr 8.2: NaHCO3 / H2O; CH2Cl2 / 23 °C / pH 8.0 View Scheme

1: methanol With acetyl chloride T=0°C; 0.5 h; 2: D-(+)-Phenylalanine 3 h; Reflux;

1: potassium bromide, sodium nitrite / H2SO4 / 1 h / 0 °C 3: 1.) hemin copolymer 1, sodium azide / 1.) water, 12 h, 2.) benzene, 6 h, 60 deg C 4: hydrogen / Pd/C View Scheme

sodium hydroxide; sodium carbonate 1 h;

1: sodium hydroxide / tetrahydrofuran; water 2: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C / |Inert atmosphere View Scheme

sodium hydroxide in diethyl ether T=20°C; 6 h;