(Z)-5-癸烯-1-醇乙酸酯合成路线 （共 44 条）
反应条件
1: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 2: pyridine / 15 h / -10 °C 3: Zn, sodium iodide / bis-(2-methoxy-ethyl) ether / 1.5 h / Heating 4: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature 5: diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 6: 91 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 1.1 p. 46 - 49
Zhurnal Organicheskoi Khimii, , vol. 26, # 1 p. 57 - 61
反应条件
1: pyridine / 15 h / -10 °C 2: Zn, sodium iodide / bis-(2-methoxy-ethyl) ether / 1.5 h / Heating 3: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature 4: diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 5: 91 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 1.1 p. 46 - 49
Zhurnal Organicheskoi Khimii, , vol. 26, # 1 p. 57 - 61
反应条件
1: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 2: pyridine / 15 h / -10 °C 3: Zn, sodium iodide / bis-(2-methoxy-ethyl) ether / 1.5 h / Heating 4: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature 5: diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 6: 91 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 1.1 p. 46 - 49
Zhurnal Organicheskoi Khimii, , vol. 26, # 1 p. 57 - 61
反应条件
1: Zn, sodium iodide / bis-(2-methoxy-ethyl) ether / 1.5 h / Heating 2: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature 3: diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 4: 91 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 1.1 p. 46 - 49
Zhurnal Organicheskoi Khimii, , vol. 26, # 1 p. 57 - 61
反应条件
1: (COCl)2, Et3N / dimethylsulfoxide; CH2Cl2 2: diethyl ether / -78 °C 3: BF3*OEt2 4: pyridine View Scheme
参考文献
Tetrahedron Letters, , vol. 34, # 23 p. 3695 - 3698
反应条件
1: diethyl ether / -78 °C 2: BF3*OEt2 3: pyridine View Scheme
参考文献
Tetrahedron Letters, , vol. 34, # 23 p. 3695 - 3698
反应条件
1: 100 percent / TsOH*pyridine / methanol / 2 h / 50 °C 2: 97 percent / DMAP, pyridine / 0.33 h / 0 °C View Scheme
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 40, # 11.1 p. 2196 - 2204
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 11 p. 2521 - 2529
反应条件
1: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature 2: diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 3: 91 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 1.1 p. 46 - 49
Zhurnal Organicheskoi Khimii, , vol. 26, # 1 p. 57 - 61
反应条件
1: 92 percent / 9-BBN; NaOH; H2O2 / tetrahydrofuran; methanol 2: 93 percent / pyridine / hexane / 2 h / 12 - 20 °C View Scheme
参考文献
Russian Chemical Bulletin, , vol. 49, # 7 p. 1301 - 1304
反应条件
1: 1.) sodiobis(trimethylsilyl)amide / 1.) THF, 50-55 deg C, 60 min, 2.) -78 deg C, 30 min; 20 deg C, 12 h 2: 60 percent / HCl / H2O; acetone / 0.5 h / 20 °C 3: 85 percent / LiAlH4 / diethyl ether / 5 h / 20 °C 4: 85 percent / pyridine / benzene / 0.67 h / 20 °C View Scheme
参考文献
Doklady Chemistry, , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., , vol. 297, # 6 p. 1381 - 1386
