(1-氨基-1-环戊烷)磷酸水合物合成路线 （共 10 条）
反应条件
1: With trimethylsilyl iodide in dichloromethane T=20°C; 6 h; Reflux; 2: With methyloxirane in ethanol 18 h;
参考文献
Rabasso, Nicolas; Fadel, Antoine
Synthesis, 2008 , # 15 art. no. T00708SS, p. 2353 - 2362
反应条件
1: 1.) BuLi / 1.) THF, -78 deg C, 30 min, 2.) THF, -78 deg C, 1 h 2: tetrahydrofuran; acetic acid / 3 h / Ambient temperature 3: 79 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 4: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: 1.) BuLi / 1.) THF, -78 deg C, 30 min, 2.) THF, -78 deg C, 1 h 2: tetrahydrofuran; acetic acid / 3 h / Ambient temperature 3: 65 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 4: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: 79 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 2: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: 65 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 2: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: acetamide With acetyl chloride in acetic acid 0.25 h; Cooling with ice; 2: methyl 2-oxo-cyclopentane-1-carboxylate With phosphorus trichoride in acetic acid T=20°C; Cooling with ice; Further stages;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 184, # 4 p. 1047 - 1053
反应条件
1: benzene / Heating 2: 90 °C 3: 60percent HBr / 6 h / 100 °C 4: 85 percent / epichlorohydrin View Scheme
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 36, # 11 p. 1392 - 1394
反应条件
hydrogenchloride 7 h; Heating;
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: 90 °C 2: 60percent HBr / 6 h / 100 °C 3: 85 percent / epichlorohydrin View Scheme
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 36, # 11 p. 1392 - 1394
反应条件
1: 60percent HBr / 6 h / 100 °C 2: 85 percent / epichlorohydrin View Scheme
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 36, # 11 p. 1392 - 1394
